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Penetrant-induced plasticization phenomenon in glassy polymers for gas separation membrane

机译:气体分离膜玻璃态聚合物中渗透剂诱导的增塑现象

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Penetrant-induced plasticization of gas separation membranes has been the subject of a number of recent investigation. The plasticization of the polymer matrix by penetrant gases can be attributed to the swelling stresses on the polymer network. It is well known that sorption of carbon dioxide in glassy polymers can facilitate the local segmental organization with a reduction in the permselectivity and substantially affect membrane morphological performance. Hence, plasticization is a phenomenon that most frequently encountered in polymer-gas systems for commercial CO_2/CH_4 separation applications where the membranes are expose to high CO_2 concentration in the feed strem. This paper attempts to present an overview of the plasticization phenomenon and the alteration of physical properties resulting from the polymer plasticization by the sorbed penetrant molecules. The plasticization suppression methods in polymeric membrane for gas separation and the future direction of research in this area are also given.
机译:渗透剂诱导的气体分离膜的增塑已成为许多近期研究的主题。渗透气体对聚合物基质的增塑作用可归因于聚合物网络上的膨胀应力。众所周知,玻璃态聚合物中二氧化碳的吸附可以促进局部节段组织的渗透选择性降低,并实质上影响膜的形态性能。因此,增塑是在商业化CO_2 / CH_4分离应用的聚合物-气体系统中最常遇到的一种现象,其中膜在进料管中暴露于高CO_2浓度。本文试图概述由吸附的渗透剂分子引起的聚合物增塑导致的增塑现象和物理性能的变化。给出了用于气体分离的聚合物膜增塑抑制方法以及该领域的研究方向。

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