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Effect of characteristics of activated carbon on removal of bromate

机译:活性炭特性对去除溴酸盐的影响

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This study evaluates how the characteristics of activated carbon (AC) influence the adsorption-reduction of bromate (BrO_3~-) by performing kinetic and isotherm tests. Experimental results reveal that both physical and chemical effects simultaneously affect the adsorption-reduction process. The wood-based carbons contained more mesopores than coconut- and coal-based carbons, resulting in the adsorption of more BrO_3~-. The equilibrium- and maximum-adsorption capacities were calculated as a function of the effect of mesopore volume. The carbon surface chemistry seems to be significant in the adsorption-reduction process. Activated carbons with high pH_(zpc) values and many basic groups exhibit a neutral or positive charge under typical pH conditions, promoting BrO_3~- adsorption-reduction at the carbon surface. The kinetic data obtained from three forms of carbons have been analyzed using three kinetic models—pseudo-first-order, pseudo-second-order and intraparticle diffusion models. Among the kinetic models studied, the intraparticle diffusion was the best applicable model to describe the adsorption of BrO_3~- onto AC.
机译:本研究通过进行动力学和等温线测试来评估活性炭(AC)的特性如何影响溴酸盐(BrO_3〜-)的吸附还原。实验结果表明,物理和化学作用同时影响吸附-还原过程。与椰子和煤基碳相比,木基碳包含更多的中孔,从而导致更多的BrO_3〜-吸附。根据中孔体积的影响计算平衡和最大吸附容量。碳表面化学在吸附还原过程中似乎很重要。具有高pH_(zpc)值和许多碱性基团的活性炭在典型的pH条件下表现出中性或正电荷,从而促进了碳表面BrO_3〜-的吸附还原。使用三种动力学模型(伪一级,伪二级和颗粒内扩散模型)分析了从三种碳形式获得的动力学数据。在研究的动力学模型中,粒子内扩散是描述BrO_3〜-在AC上的吸附的最佳适用模型。

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