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Treating sulfur black dye wastewater with quaternized poly (phthalazinone ether sulfone ketone) nanofiltration membranes

机译:季铵化聚(酞嗪酮醚砜酮)纳滤膜处理含硫黑染料废水

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摘要

Two kinds of nanofiltration (NF) membranes were investigated in treating the Sulfur Black B dye wastewater. Negatively charged polypiperazine amide/poly (phthalazinone ether sulfone ketone) (PIP/PPESK) NF membrane was prepared by interfacial polymerization method while positively charged quaternized poly (phthalazinone ether sulfone ketone) (QAPPESK) membrane was prepared by phase inversion method. QAPPESK NF membrane was selected for further study because it performed higher dye rejection and flux compared with the PIP/PPESK NF membrane. The effects of different operation conditions were systematically studied based on the rejection and desalination of the dye. Over 14.5 L/m2 h flux, 92.3% dye rejection and 10% salts rejection were observed in the long term operation at 60 °C which indicated that the QAPPESK membranes could be successfully applied in the sulfur black dye wastewater treatment and inorganic salts reuse.
机译:研究了两种纳滤膜(NF)在处理硫化黑B染料废水中的应用。通过界面聚合法制备带负电荷的聚哌嗪酰胺/聚(酞嗪酮醚砜酮)(PIP / PPESK)NF膜,通过相转化法制备带正电荷的季铵化聚(酞嗪酮醚酮)(QAPPESK)膜。选择QAPPESK NF膜进行进一步研究,因为与PIP / PPESK NF膜相比,它具有更高的染料截留率和通量。基于染料的排斥和脱盐,系统地研究了不同操作条件的影响。在60°C的长期运行中,超过14.5 L / m2 h的通量,观察到92.3%的染料截留率和10%的盐截留率,这表明QAPPESK膜可以成功地用于硫化黑染料废水处理和无机盐的再利用。

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