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Ni-YSZ cermet anode fabricated from NiO-YSZ composite powder for high-performance and durability of solid oxide fuel cells

机译:由NiO-YSZ复合粉末制成的Ni-YSZ金属陶瓷阳极,可提高固体氧化物燃料电池的性能和耐用性

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摘要

A functional composite powder, in which Dano-sized NiO (40 vol.%) was crystallized on YSZ particles, was synthesized by the Pechini-type polymerizable complex method in an effort to improve the performance and durability of SOFC anodes. The pore-structure (e.g. porosity, pore size) and mechanical properties (e.g. strength, density) of the electrode were optimized by a combination of two different species of YSZ powder (Tosoh 0.3 mu m and Millennium 10 mu m). A single cell made from the composite powder exhibited high power density of 1.1 W cm(-2) and high durability under a load of 1.0 A cm(-2) during 530 h of operating time at 800 degrees C. It could be concluded that this functional composite would enhance the single cell performance and durability at elevated temperature. (C) 2007 Elsevier B.V. All rights reserved.
机译:为了改善SOFC阳极的性能和耐久性,通过Pechini型可聚合络合物方法合成了在YSZ颗粒上结晶有Dano尺寸的NiO(40体积%)的功能性复合粉末。通过两种不同种类的YSZ粉末(Tosoh 0.3微米和Millennium 10微米)的组合来优化电极的孔结构(例如孔隙度,孔径)和机械性能(例如强度,密度)。由复合粉末制成的单个电池在800摄氏度的530小时工作时间内,在1.0 A cm(-2)的负载下表现出1.1 W cm(-2)的高功率密度和高耐久性。可以得出结论:这种功能性复合材料可提高单电池的性能和在高温下的耐久性。 (C)2007 Elsevier B.V.保留所有权利。

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