IR and Raman spectra of two layered aluminium phosphates Co(en)(3)Al(3)P(4)O16 center dot 3H(2)O and [NH4](3)[Co(NH3)(6)](3)[Al-2(PO4)(4)]center dot 2H(2)O

John A.; Morgan KR.; Devanarayanan S.; Philip D.

首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >IR and Raman spectra of two layered aluminium phosphates Co(en)(3)Al(3)P(4)O16 center dot 3H(2)O and [NH4](3)[Co(NH3)(6)](3)[Al-2(PO4)(4)]center dot 2H(2)O

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IR and Raman spectra of two layered aluminium phosphates Co(en)(3)Al(3)P(4)O16 center dot 3H(2)O and [NH4](3)[Co(NH3)(6)](3)[Al-2(PO4)(4)]center dot 2H(2)O

机译：两层磷酸铝Co（en）（3）Al（3）P（4）O16中心点3H（2）O和[NH4]（3）[Co（NH3）（6）]（3的红外光谱和拉曼光谱）[Al-2（PO4）（4）]中心点2H（2）O

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The FT IR and FT Raman spectra of Co(en)(3)Al3P4O16 . 3H(2)O (compound I) and [NH4](3)[Co(NH3)(6)](3)[Al-2 (PO4)(4)](2) . 2H(2)O (compound II) are recorded and analysed based on the vibrations of Co(en)(3)(3+), Co(NH3)(6)(3+), NH4+, Al-O-P, PO3, PO2 and H2O. The observed splitting of bands indicate that the site symmetry and correlation field effects are appreciable in both the compounds. In compound I, the overtone of CH2 deformation Fermi resonates with its symmetric stretching vibration. The NH4 ion in compound II is not free to rotate in the crystalline lattice. Hydrogen bonding of different groups is also discussed. (C) 2000 Elsevier Science B.V. All rights reserved. [References: 39]

机译：Co（en）（3）Al3P4O16的FT IR和FT拉曼光谱。 3H（2）O（化合物I）和[NH4]（3）[Co（NH3）（6）]（3）[Al-2（PO4）（4）]（2）。根据Co（en）（3）（3 +），Co（NH3）（6）（3 +），NH4 +，Al-OP，PO3的振动记录和分析2H（2）O（化合物II） PO2和H2O。观察到的谱带分裂表明在两种化合物中位点对称性和相关场效应都是明显的。在化合物I中，CH2变形费米的泛音与其对称的拉伸振动产生共振。化合物II中的NH4离子不能在晶格中自由旋转。还讨论了不同基团的氢键。（C）2000 Elsevier Science B.V.保留所有权利。 [参考：39]

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《Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy》 |2000年第14期|共9页
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John A.; Morgan KR.; Devanarayanan S.; Philip D.;
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Vibrational spectra; Aluminium phosphates; Co(en)(3)(3)+ ion; Co(nh3)(6)(3+) ion; Vibrational-spectra; Ethylenediamine complexes; Infrared-spectra; Ammine complexes; Force-constants; Tris(ethylenediamine);

机译：振动光谱;磷酸铝;Co（en）（3）（3）+离子;Co（nh3）（6）（3+）离子;振动光谱;乙二胺配合物;红外光谱;氨配合物;力常数;三（乙二胺）;

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1. IR and Raman spectra of two layered aluminium phosphates Co(en)(3)Al(3)P(4)O16 center dot 3H(2)O and [NH4](3)[Co(NH3)(6)](3)[Al-2(PO4)(4)]center dot 2H(2)O [J] . John A., Morgan KR., Devanarayanan S., Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2000,第14期

机译：两层磷酸铝Co（en）（3）Al（3）P（4）O16中心点3H（2）O和[NH4]（3）[Co（NH3）（6）]（3的红外光谱和拉曼光谱）[Al-2（PO4）（4）]中心点2H（2）O
2. THE FIRST ORGANICALLY TEMPLATED LAYERED COBALT PHOSPHATES - HYDROTHERMAL SYNTHESES AND CRYSTAL STRUCTURES OF [H3N(CH2)(3)NH3](0.5)[CO(PO4)]CENTER-DOT-0.5H2O AND [H3N(CH2)(4)NH3](0.5)[CO(PO4)] [J] . Debord JRD., Zubieta J., Haushalter RC. International Journal of Quantum Chemistry . 1996,第2期

机译：[H3N（CH2）（3）NH3]（0.5）[CO（PO4）] CENTER-DOT-0.5H2O和[H3N（CH2）（4）NH3]的第一有机模板层状钴磷酸盐的水热合成和晶体结构（0.5）[CO（PO4）]
3. H3N(CH2)(6)NH3 center dot Zn-4(PO4)(2)(HPO4)(2)center dot 3H(2)O: a novel three-dimensional zinc phosphate framework containing 5- and 20-rings [J] . Rodgers JA., Harrison WTA. Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2000,第12期

机译：H3N（CH2）（6）NH3中心点Zn-4（PO4）（2）（HPO4）（2）中心点3H（2）O：新颖的三维磷酸锌骨架，含5和20个环
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7. 6-(4-Bromophenyl)-6,7-dihydro-1,3-dioxolo[4,5-g]quinolin-8(5H)-one: bilayers built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds [O] . Low, J N, Cobo, J, Cuervo, P, 2004

机译：6-（4-溴苯基）-6,7-二氢-1,3-二氧杂环戊[4,5-g]喹啉-8（5H）-one：由NH中心点中心点中心点O，CH中心点构成的双层中心点中心点O和CH中心点中心点中心点pi（芳烃）氢键

IR and Raman spectra of two layered aluminium phosphates Co(en)(3)Al(3)P(4)O16 center dot 3H(2)O and [NH4](3)[Co(NH3)(6)](3)[Al-2(PO4)(4)]center dot 2H(2)O

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