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首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >Vibrational analysis of Ag-3(PO2NH)(3), Na-3(PO2NH)(3 center dot)H2O, Na-3(PO2NH)(3 center dot)4H(2)O, [C(NH2)(3)](3)(PO2NH)(3 center dot)H2O and (NH4)(4)(PO2NH)(4 center dot)4H(2)O
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Vibrational analysis of Ag-3(PO2NH)(3), Na-3(PO2NH)(3 center dot)H2O, Na-3(PO2NH)(3 center dot)4H(2)O, [C(NH2)(3)](3)(PO2NH)(3 center dot)H2O and (NH4)(4)(PO2NH)(4 center dot)4H(2)O

机译:Ag-3(PO2NH)(3),Na-3(PO2NH)(3中心点)H2O,Na-3(PO2NH)(3中心点)4H(2)O,[C(NH2)(3)的振动分析)](3)(PO2NH)(3个中心点)H2O和(NH4)(4)(PO2NH)(4个中心点)4H(2)O

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摘要

FT IR and FT Raman spectra of Ag-3(PO2NH), (Compound I), Na-3(PO2NH)(3).H2O (Compound II), Na-3(PO2NH)(3).4H(2)O (Compound III), [C(NH2)(3)(PO2NH)(3).H2O (Compound IV) and (NH4)(4)(PO2NH)(4).4H(2)O (Compound V) are recorded and analyzed on the basis of the anions, cations and water molecules present in each of them. The PO2NH- anion ring in compound I is distorted due to the influence of Ag+ cation. Wide variation in the hydrogen bond lengths in compound III is indicated by the splitting of the v(2) and v(3) modes of vibration of water molecules. The NH4 ion in compound V occupies lower site symmetry and exhibits hindered rotation in the lattice. The correlations between the symmetric and asymmetric stretching vibrations of P-N-P bridge and the P-N-P bond angle have also been discussed. (C) 2001 Elsevier Science B.V. All rights reserved. [References: 36]
机译:Ag-3(PO2NH),(化合物I),Na-3(PO2NH)(3).H2O(化合物II),Na-3(PO2NH)(3).4H(2)O的FT IR和FT拉曼光谱(化合物III),[C(NH2)(3)(PO2NH)(3).H2O(化合物IV)和(NH4)(4)(PO2NH)(4).4H(2)O(化合物V)被记录并根据它们各自存在的阴离子,阳离子和水分子进行分析。化合物I中的PO2NH-阴离子环由于Ag +阳离子的影响而变形。水分子振动的v(2)和v(3)振动模式的分裂表明化合物III中氢键长度的广泛变化。化合物V中的NH4离子占据较低的位点对称性,并在晶格中表现出受阻的旋转。还讨论了P-N-P桥的对称和非对称拉伸振动与P-N-P键角之间的关系。 (C)2001 Elsevier Science B.V.保留所有权利。 [参考:36]

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