Spectral, redox and catalytic studies of triphenylphosphine/triphenylarsine complexes of Ru(III) with N, O donor ligands derived from 2-hydroxy-1-naphthaldehyde and primary amines

Mahalingam V; Karvembu R; Chinnusamy V; Natarajan K

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Spectral, redox and catalytic studies of triphenylphosphine/triphenylarsine complexes of Ru(III) with N, O donor ligands derived from 2-hydroxy-1-naphthaldehyde and primary amines

机译：Ru（III）与由2-羟基-1-萘醛和伯胺衍生的N，O供体配体的三苯基膦/三苯基phenyl络合物的光谱，氧化还原和催化研究

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A series of new mixed ligand hexacoordinated ruthenium(III) Schiff base complexes of the type [RuX2(EPh3)(2)(LL')] (X=Cl, E=P; X=Cl or Br, E=As and LL'=anion of the Schiff bases derived from the condensation of 2-hydroxy-1-naphthaldehyde with aniline, 4-chloroaniline, 2-methyl aniline and 4-methoxy aniline) are reported. All the complexes have been characterized by analytical and spectral (IR, electronic and EPR) data. The redox behavior of the complexes has also been studied. The complexes exhibit catalytic activity in the oxidation of benzyl alcohol to benzaldehyde in the presence of N-methyl morpholine-N-oxide (NMO). An octahedral structure has been proposed for all of the complexes. (c) 2005 Elsevier B.V. All rights reserved.

机译：[RuX2（EPh3）（2）（LL'）]类型的一系列新的混合配体六配位钌（III）席夫碱配合物（X = Cl，E = P; X = Cl或Br，E = As和LL报道了由2-羟基-1-萘醛与苯胺，4-氯苯胺，2-甲基苯胺和4-甲氧基苯胺缩合得到的席夫碱的阴离子。所有配合物均已通过分析和光谱（红外，电子和EPR）数据进行了表征。还研究了配合物的氧化还原行为。在N-甲基吗啉-N-氧化物（NMO）存在下，该配合物在苯甲醇氧化为苯甲醛中表现出催化活性。已经为所有复合物提出了八面体结构。（c）2005 Elsevier B.V.保留所有权利。

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《Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy》 |2006年第4期|共5页
作者
Mahalingam V; Karvembu R; Chinnusamy V; Natarajan K;
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正文语种 eng
中图分类分析化学;
关键词
ruthenium(III); spectroscopic characterization; cyclic voltammetry; catalytic oxidation; SCHIFF-BASE COMPLEXES; RUTHENIUM(III) COMPLEXES; BIOLOGICAL-ACTIVITY; AEROBIC OXIDATION; TRIPHENYLARSINE; ALCOHOLS; ALDEHYDES; EFFICIENT; KETONES; OXO;

机译：钌（III）;光谱表征;循环伏安法;催化氧化;SCHIFF基络合物;钌（III）络合物;生物活性;需氧氧化;三苯甲氨酸;醇;醛;高效;酮;氧;

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1. Spectral, redox and catalytic studies of triphenylphosphine/triphenylarsine complexes of Ru(III) with N, O donor ligands derived from 2-hydroxy-1-naphthaldehyde and primary amines [J] . Mahalingam V, Karvembu R, Chinnusamy V, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2006,第4期

机译：Ru（III）与由2-羟基-1-萘醛和伯胺衍生的N，O供体配体的三苯基膦/三苯基phenyl络合物的光谱，氧化还原和催化研究
2. Thiobis(beta-diketonato)-bridged binuclear ruthenium(III) complexes containing triphenylphosphine or triphenylarsine. Synthetic, spectral, catalytic and antimicrobial studies [J] . Ramasamy Karvembu, Chinnasamy Jayabalakrishnan, Karuppannan Natarajan Transition Metal Chemistry . 2002,第6期

机译：含三苯膦或三苯ar的硫双（β-二酮基）桥连双核钌（III）配合物。合成，光谱，催化和抗菌研究
3. Preparation,spectral characterization,electrochemistry,EXAFS,antibacterial and catalytic activity of new ruthenium (III) complexes containing ONS donor ligands with triphenylphosphine/arsine [J] . R.Prabhakaran, V.Krishnan, K.Pasumpon, Applied Organometallic Chemistry . 2006,第3期

机译：含ONS供体配体与三苯基膦/ ar的新型钌（III）配合物的制备，光谱表征，电化学，EXAFS，抗菌和催化活性
4. Intramolecular Arene Displacement Reaction of Ru Complexes Bearing a Primary Amine Ligand with Aromatic Moiety [C] . Masato Ito, Hiroko Komatsu, Takao Ikariya Symposium on Organometallic Chemistry . 2004

机译：Ru复合物的分子内芳烃位移反应轴承伯胺配体与芳族部分
5. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

机译：Ru和Mn的一系列高价羰基配合物的结构和反应性：Ru（III）介导的三苯膦催化氧化，双核Mn（III，III）和Mn（III，IV）二聚体的表征以及单核铁（III）和铁（IV）。
6. Studies on Some New Ru(III) Complexes Using aryl-azo Pentane-2,4-dione and 2,6-bis (2'-Benzimidazolyl) Pyridine as Ligands:Synthesis, Spectroscopic, Luminescent, Electrochemical and Biological Activities [O] . Lallan Mishra, Ajay K. Yadaw, Ratna S. Phadke, 1947

机译：用芳基偶氮戊烷-研究一些新的Ru（III）配合物2,4-二酮和2,6-双（2'-苯并咪唑基）吡啶为配体：合成，光谱，发光，电化学和生物活性
7. Synthesis, spectral characterization, catalytic andbiological studies of new Ru(II) carbonyl Schiff base complexes of active amines [O] . Vellalapalayam Vangaiannan Raju, Kugalur Palanisamy Balasubramanian, Chinnasamy Jayabalakrishnan, 2011

机译：新型活性胺Ru（II）羰基席夫碱配合物的合成，光谱表征，催化生物学研究

Spectral, redox and catalytic studies of triphenylphosphine/triphenylarsine complexes of Ru(III) with N, O donor ligands derived from 2-hydroxy-1-naphthaldehyde and primary amines

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