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首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >Photophysical processes of a fluorene derivative containing carbazole unit
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Photophysical processes of a fluorene derivative containing carbazole unit

机译：含咔唑单元的芴衍生物的光物理过程

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摘要

The photoluminescence properties of 9,9-bis[4'-(9"-carbazovinylene)phenyl]fluorene (F-CZV) formed by Heck reaction of 9,9-bis(4'-iodophenyl)fluorene (F-IP) and N-vinylcarbazole have been carefully studied. The results show that the compound emits blue light and the dimolecular excimer is formed with gradual increase in concentration of F-CZV. The results also indicate the interaction between F-CZV and electron donors (N,N-dimethylaniline) or electron acceptors (dimethylterephthalate, fullerene carbon nanotubes) can be efficiently generated where the processes follow the Stern-Volmer equation. Moreover, when dimethylterephthalate (DMTP) or carbon nanotubes (CNTs) is gradually added into the solution of F-CZV, the emission intensities of fluorescence are unusually increased. But when concentration of dimethylterephthalate or carbon nanotubes beyond a certain scope, the emission intensities of fluorescence are gradually decreased. (c) 2004 Elsevier B.V. All rights reserved.
机译：通过9,9-双（4'-碘苯基）芴（F-IP）的Heck反应形成的9,9-双[4'-（9“-咔唑亚乙烯基）苯基]芴（F-CZV）的光致发光特性N-乙烯基咔唑经过仔细研究，结果表明该化合物发出蓝光，并随着F-CZV浓度的逐渐增加而形成二分子准分子，该结果还表明F-CZV与电子给体之间的相互作用（N，N遵循Stern-Volmer方程的过程中，可以高效地生成-对二甲苯基苯胺）或电子受体（对苯二甲酸二甲酯，富勒烯碳纳米管），然后在F-CZV溶液中逐渐添加对苯二甲酸二甲酯（DMTP）或碳纳米管（CNT）。 ，荧光的发射强度异常增加，但是当对苯二甲酸二甲酯或碳纳米管的浓度超过一定范围时，荧光的发射强度逐渐降低（c）2004 Elsevier BV保留所有权利。

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