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首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >High luminescence quantum yields and long luminescence lifetime from Eu(III) complex containing two crystal water based on a new beta-diketonate ligand
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High luminescence quantum yields and long luminescence lifetime from Eu(III) complex containing two crystal water based on a new beta-diketonate ligand

机译:含两种基于新的β-二酮酸酯配体的结晶水的Eu(III)配合物的高发光量子产率和长发光寿命

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摘要

New members of family of Eu(III) complex based on the thenoylacetophenone have been synthesized and characterized. The compounds were found for high metal luminescence quantum yields and Iona luminescence lifetime, especially for compound with two crystal water, corresponding with other compounds containing two crystal water. The result is attributed to high molar absorption coefficients of the Eu(III) complex according to UV-vis and emission spectra. The high molar absorption coefficients balance quenching effect from O-H oscillators of water contained in compound. (c) 2005 Elsevier B.V. All rights reserved.
机译:合成和表征了基于壬酰基苯乙酮的Eu(III)配合物家族的新成员。发现该化合物具有高的金属发光量子产率和Iona发光寿命,特别是对于具有两个结晶水的化合物,与具有两个结晶水的其他化合物相对应。该结果归因于根据紫外可见光谱和发射光谱的Eu(III)络合物的高摩尔吸收系数。高摩尔吸收系数平衡了化合物中所含水的O-H振荡器的猝灭作用。 (c)2005 Elsevier B.V.保留所有权利。

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