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首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >Electron paramagnetic resonance study on manganese doped tetrathioureacopper(I) chloride single crystal
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Electron paramagnetic resonance study on manganese doped tetrathioureacopper(I) chloride single crystal

机译:锰掺杂四硫脲铜(I)单晶的电子顺磁共振研究

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摘要

Electron paramagnetic resonance (EPR) spectrum of a NLO material, manganese doped tetrathioureacopper(I) chloride single crystal was investigated at room temperature. The spectra reveal that manganese exists in tetravalent state in the host lattice in interstitial position and the crystal becomes NLO material whereas the pure crystal does not show NLO property. The spin Hamiltonian parameters are evaluated as g = 1.9872 and A = 157 G. The transmission spectrum and the second harmonic generation efficiency confirm that the manganese doped single crystal exhibit NLO property. (c) 2006 Published by Elsevier B.V.
机译:在室温下研究了NLO材料锰掺杂的氯化四硫脲铜(I)单晶的电子顺磁共振(EPR)光谱。光谱显示锰在间隙位置以四价态存在于主体晶格中,并且晶体变为NLO材料,而纯晶体不显示NLO性质。自旋哈密顿量参数的评估值为g = 1.9872和A = 157G。透射光谱和二次谐波产生效率确认了锰掺杂的单晶具有NLO性能。 (c)2006年由Elsevier B.V.发布

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