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首页> 外文期刊>Chemical Society Reviews >The oxygen scavenging properties of alkali metal-containing organometallic compounds
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The oxygen scavenging properties of alkali metal-containing organometallic compounds

机译：含碱金属的有机金属化合物的除氧性能

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摘要

Alkali metal-containing organometallic compounds are well known for their oxophilicity and, as a result, reactions utilising them must be carried out under an inert atmosphere with oxygen having to be scrupulously removed from the system if these complexes are to be successfully synthesized, manipulated or employed. Studies will be presented here which investigated to oxophilic nature of alkali metal-containing organometallic species. The route by which oxygen is scavenged from the environment will be considered, as will different effects to be had by varying the oxygen source. Discussion will focus primarily on the metal organo- and inorganooxide and oxide or peroxide coordination complex structural motifs which result from the reaction of oxophilic substrates.
机译：含碱金属的有机金属化合物具有亲氧性，因此使用它们的反应必须在惰性气氛下进行，如果要成功合成，处理或络合这些化合物，必须从系统中严格除去氧气受雇。这里将进行研究，以研究含碱金属的有机金属物质的亲氧性质。将考虑从环境中清除氧气的途径，以及通过改变氧气源而产生的不同影响。讨论将主要集中于由亲氧性底物的反应产生的金属有机和无机氧化物以及氧化物或过氧化物配位化合物的复杂结构基序。

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