Novel and Efficient Approach to Fluorinated beta-Aminobutanones Catalyzed by Molecular Iodine

Min Xia; Yue-dong Lu

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Novel and Efficient Approach to Fluorinated beta-Aminobutanones Catalyzed by Molecular Iodine

机译：分子碘催化新型高效氟化氟化β-氨基丁酮

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摘要

A variety of fluorinated compounds of beta-amino ketones could be obtained in good to excellent yields at room temperature through a three-component Mannich reaction of aldehydes,anilines,and acetones catalyzed by iodine.

机译：通过碘催化的醛，苯胺和丙酮的三组分曼尼希反应，可以在室温下以良好或优异的收率获得各种氟化的β-氨基酮化合物。

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《Synthetic Communications》 |2007年第6期|共11页
作者
Min Xia; Yue-dong Lu;
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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
beta-aminobutanones; catalysis; iodine; Mannich;

机译：β-氨基丁酮;催化;碘;曼尼希;

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专利

1. Novel and Efficient Approach to Fluorinated beta-Aminobutanones Catalyzed by Molecular Iodine [J] . Min Xia, Yue-dong Lu Synthetic Communications . 2007,第4a6期

机译：分子碘催化新型高效氟化氟化β-氨基丁酮
2. Pd-Catalyzed Regioselective Activation of gem-Difluorinated Cyclopropanes: A Highly Efficient Approach to 2-Fluorinated Allylic Scaffolds [J] . Xu Jun, Ahmed Ebrahim-Alkhalil, Xiao Bin, Angewandte Chemie . 2015,第28期

机译：钯催化的宝石二氟环丙烷的区域选择性活化：一种高效的2-氟代烯丙基支架的方法。
3. An efficient route to synthesize isatins by metal-free, iodine-catalyzed sequential C(sp~3)-H oxidation and intramolecular C-N bond formation of 2'-aminoacetophenones [J] . Venkatachalam Rajeshkumar, Selvaraj Chandrasekar, Govindasamy Sekar Organic & biomolecular chemistry . 2014,第42期

机译：通过无金属，碘催化的连续C（sp〜3）-H氧化和2'-氨基苯乙酮的分子内C-N键形成来合成isatins的有效途径
4. Pd-Catalyzed Intramolecular Cyclization of Fluorinated Imidoyl Chloride: Synthesis of Fluorinated Quinolines [C] . Akira Isobe, Jun Takagi, Kenji Uneyama Symposium on Organometallic Chemistry . 2006

机译：PD催化氟化咪唑氯的分子内环化：氟化喹啉的合成
5. Molecular engineering of glutathione S-transferase to identify mutants that more efficiently catalyze the conjugation of glutathione with an anti-cancer agent [D] . Gulick, Andrew M. 1995

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6. Molecular Iodine-Catalyzed Selective C-3 Benzylationof Indoles with Benzylic Alcohols: A Greener Approach toward BenzylatedIndoles [O] . Prantika Bhattacharjee, Utpal Bora, * 2019

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7. Highly Efficient Chemoselective Deprotection of O, O-Acetals and O, O-Ketals Catalyzed by Molecular Iodine in Acetone [O] . -1

机译：高效的丙酮中催化的O，O-缩醛和O，O-丙酮的溶解剂

Novel and Efficient Approach to Fluorinated beta-Aminobutanones Catalyzed by Molecular Iodine

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