Nazarov approach to 4-benzoyloxymethyl-cyclopent-2-enone, a precursor to the helminthosporols

Belardi JK; Curtis LA; Clareen SS; Shimp HL; Leimkuhler CE; Simonowicz NL; Casillas E

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Nazarov approach to 4-benzoyloxymethyl-cyclopent-2-enone, a precursor to the helminthosporols

机译：纳扎罗夫制备4-苯甲酰氧基甲基-环戊-2-烯酮的方法

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摘要

A short, scalable route to 4-hydroxymethylcyclopent-2-enone, based upon a silicon-directed Nazarov cyclization, is described. Noteworthy in this study is the success of the cyclization with an oxygenated substrate.

机译：描述了基于硅定向的Nazarov环化的4-羟甲基环戊-2-烯酮的短而可扩展的路线。在这项研究中值得注意的是用含氧底物进行环化的成功。

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来源
《Synthetic Communications》 |2005年第12期|共8页
作者
Belardi JK; Curtis LA; Clareen SS; Shimp HL; Leimkuhler CE; Simonowicz NL; Casillas E;
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正文语种 eng
中图分类有机化学;
关键词
BF3-etherate; divinylcyclopropane rearrangement; silicon-directed Nazarov; KHAND REACTION; REARRANGEMENT; CYCLIZATIONS; CONVENIENT; ROUTE;

机译：BF3-醚酸酯;二乙烯基环丙烷重排;硅基纳扎罗夫;KHAND反应;重排;循环;便利;路线;

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1. Nazarov approach to 4-benzoyloxymethyl-cyclopent-2-enone, a precursor to the helminthosporols [J] . Belardi JK, Curtis LA, Clareen SS, Synthetic Communications . 2005,第12期

机译：纳扎罗夫制备4-苯甲酰氧基甲基-环戊-2-烯酮的方法
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Nazarov approach to 4-benzoyloxymethyl-cyclopent-2-enone, a precursor to the helminthosporols

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