A NEW PROCEDURE FOR ALPHA-HYDROXYLATION OF KETONES USING THALLIUM(III) P-NITROBENZENESULFONATE (TNS)

Lee JC.; Choi Y.; Park C.

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A NEW PROCEDURE FOR ALPHA-HYDROXYLATION OF KETONES USING THALLIUM(III) P-NITROBENZENESULFONATE (TNS)

机译：ALL（III）对-硝基苯磺酸盐（TNS）对酮进行羟基加氢氧化的新方法

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An efficient method for conversion of ketones to alpha-hydroxyketones by treatment of thallium(III) p-nitrobenzenesulfonate with ketones and subsequent hydrolysis using DMSO/H2O in one pot system is described. [References: 9]

机译：描述了一种通过用酮处理对硝基苯磺酸al（III），然后在一个罐系统中使用DMSO / H2O进行水解的方法，将酮转化为α-羟基酮的有效方法。 [参考：9]

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《Synthetic Communications》 |1997年第23期|共6页
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Lee JC.; Choi Y.; Park C.;
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正文语种 eng
中图分类有机化学;
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1. A NEW PROCEDURE FOR ALPHA-HYDROXYLATION OF KETONES USING THALLIUM(III) P-NITROBENZENESULFONATE (TNS) [J] . Lee JC., Choi Y., Park C. Synthetic Communications . 1997,第23期

机译：ALL（III）对-硝基苯磺酸盐（TNS）对酮进行羟基加氢氧化的新方法
2. Rearrangement of homoallylic alcohols with thallium(III): Diastereoselective synthesis of Indans bearing a beta-hydroxy ketone moiety [J] . Silva LF, Quintiliano SAP, Craveiro MV, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2007,第3期

机译：ally（III）均丙醇的重排：带有β-羟基酮部分的茚满的非对映选择性合成
3. A Facile Procedure for Acetalization of Aldehydes and Ketones Catalyzed by Cerium(III)Trifluoromethanesulfonate [J] . Fumiaki Ono, Yoshiko Inatomi, Yuusuke Tada Chemistry Letters . 2009,第1期

机译：三氟甲烷磺酸铈（III）催化醛和酮缩醛的简便方法
4. Preparation of magnetic chitosan-?-cyclodextrin polymer and its adsorption for thallium (III) in aqueous solution [C] . Zhiwu Zhou, Jingsong Wang, Qingwei Guo International Conference on Manufacturing Science and Engineering . 2012

机译：磁性壳聚糖 - α - 环糊精聚合物的制备及其对水溶液中铊（III）的吸附
5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
6. Synthesis Characterization and Antibacterial Studies of N-(Benzothiazol-2-yl)-4-chlorobenzenesulphonamide and Its Neodymium(III) and Thallium(III) Complexes [O] . Lawrence Nnamdi Obasi, Uchechukwu Susan Oruma, Ibrahim Abdulrazak Al-Swaidan, 2017

机译：N-（苯并噻唑-2-基）-4-氯苯磺酰胺及其钕（III）和hall（III）配合物的合成表征和抗菌研究
7. A Kinetic Study of the Isotopic Exchange of Thallium(III) between the Thallium(III) Ion and the ThalliumN-2-Hydroxyethylethylenediamine-N,N′,N′-triacetate Complex in Water [O] . Michiko Tsuchimoto 1965

机译：铊（III）离子与铊（III）离子与铊（III）与铊 - 2-羟乙基乙基二胺 - N，N'，N'-三乙酸酯复合物在水中的动力学研究

A NEW PROCEDURE FOR ALPHA-HYDROXYLATION OF KETONES USING THALLIUM(III) P-NITROBENZENESULFONATE (TNS)

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