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首页> 外文期刊>Synthetic Metals >Structural models of stage-2 graphite hexafluoroarsenates C_xAsF_6 and the derivation of XRD intensity expressions of the 10 band fine structures
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Structural models of stage-2 graphite hexafluoroarsenates C_xAsF_6 and the derivation of XRD intensity expressions of the 10 band fine structures

机译:第二阶段六氟砷化石墨C_xAsF_6的结构模型和10带精细结构的XRD强度表达式的推导

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摘要

The structural models for the stage-2 C_(28)AsF_6 and C_xAsF_6 (x approx = 25) graphite intercalation compounds with nestled and un-nestled AsF_6~-, respectively, are presented. The stacking sequences are random in both compounds, but they differ in the relative arrangement of the two graphite layers sandwiching the intercalate layer and are expressed by A|BC|AC|BA|C… and A|AB|BA|AC|C…,respectively, where | denotes the AsF_6~- intercalate layer. The mathematical derivations for the fine structure profiles of their 10 bands of X-ray diffraction are given.
机译:给出了第二阶段C_(28)AsF_6和C_xAsF_6(x大约= 25)带有嵌套和未嵌套AsF_6-的石墨插层化合物的结构模型。两种化合物的堆积顺序是随机的,但是它们之间夹着插入层的两个石墨层的相对排列不同,用A | BC | AC | BA | C…和A | AB | BA | AC | C…表示。分别表示AsF_6〜-插入层。给出了其10个X射线衍射带的精细结构轮廓的数学推导。

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