CONVENIENT SYNTHESIS OF 1,3,6-TRIENE SYSTEMS THROUGH ALKYLATION OF 3-METHYL-3-SULFOLENE

Subramanian T.; Bhat SV.; Padmakumar R.

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CONVENIENT SYNTHESIS OF 1,3,6-TRIENE SYSTEMS THROUGH ALKYLATION OF 3-METHYL-3-SULFOLENE

机译：通过3-甲基-3-丁烯的烷基化方便地合成1,3,6-三烯体系

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Various 1,3,6-triene systems have been synthesised through alkylation of 3-methyl-3-sulfolene with conjugated aldehydes followed by silylation and subsequent desulfonylation. A new route to synthesis of (+/-)-alpha-chamigrene, isofokienol and 5-hydroxy-alpha-farnesene has been described. [References: 12]

机译：通过3-甲基-3-环丁砜与共轭醛的烷基化，然后进行甲硅烷基化和随后的脱磺酰基反应，已经合成了各种1,3,6-三烯系统。已经描述了合成（+/-）-α-香豆烯，异氟酮醇和5-羟基-α-法呢烯的新途径。 [参考：12]

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《Synthetic Communications》 |1997年第23期|共6页
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Subramanian T.; Bhat SV.; Padmakumar R.;
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1. CONVENIENT SYNTHESIS OF 1,3,6-TRIENE SYSTEMS THROUGH ALKYLATION OF 3-METHYL-3-SULFOLENE [J] . Subramanian T., Bhat SV., Padmakumar R. Synthetic Communications . 1997,第23期

机译：通过3-甲基-3-丁烯的烷基化方便地合成1,3,6-三烯体系
2. Chiral 1,3,6-trisubstituted 2,4-dioxohexahydropyrimidines:a convenient stereoselective synthesis from aspartic acid derivatives [J] . Rosario Patino-Molina, Ivan Cubero-Lajo, M.Jesus Perez de Vega Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007,第20期

机译：手性1,3,6-三取代的2,4-二氧六氢嘧啶：从天冬氨酸衍生物方便的立体选择性合成
3. A Convenient Synthesis of Functionalized 2,3-Diazaspiro[4.4]nona-1,6,8-trienes [J] . Issa Yavari, Jamil Sheykhahmadi, Samira Bahemat, Synlett . 2018,第15期

机译：方便合成官能化2,3-diazaspiro [4.4]非A-1,6,8-三烯
4. AN IMPROVED ROBINSON ANNELATION PROCESS VIA REDUCTIVE ALKYLATION OF THE γ-CYANO-α,β-UNSATURATED KETONE SYSTEM.APPLICATION TO THE TOTAL SYNTHESIS OF (±)-NANAIMOAL [C] . Hsing-Jang Liu International symposium for Chinese organic chemists . 2000

机译：通过γ-氰基-α，β-不饱和酮体系的还原烷基化改进的罗宾逊结合方法。应用于（±） - 南部的总合成
5. Part A. Diastereoselective synthesis of protected secondary amines via reduction /alkylation or deprotonation /alkylation of N-diphenylphosphinylimines. Part B. Synthesis of secondary amines via 1,2-addition of organometallic reagents to N-diphenylphosphinylimines and subsequent alkylation [D] . Shin, Hyunshun 2001

机译：A部分：通过N-二苯基膦亚胺的还原/烷基化或去质子化/烷基化的非对映选择性合成保护的仲胺。 B部分：通过将有机金属试剂1,2-加成到N-二苯基膦亚胺和随后的烷基化反应来合成仲胺
6. An Efficient Second-Generation Synthesis of the Signature Dioxabicyclo3.2.1octane Core of (+)-Sorangicin A and Elaboration of the (ZZE)-Triene Acid System [O] . Amos B. Smith III, Shuzhi Dong -1

机译：一种高效的签名的第二代合成二氧杂双环3.2.1辛烷核心（+） - sorangicin a和精化的（ZZE） - 三烯的酸体系
7. Convenient synthesis of cyclic α-aminophosphonates by alkylation-cyclization reaction of iminophosphoglycinates using phase-transfer catalysis [O] . Ramírez-Marroquín Oscar Abelardo, Romero-Estudillo Iván, Viveros-Ceballos José Luis, 2017

机译：通过相转移催化亚氨基磷酸甘氨酸盐的烷基化-环化反应方便地合成环状α-氨基膦酸盐
8. Synthesis and Dimerization of Two Cross-Conjugated Trienes: 3-Methylene-1,4-Pentadiene and 1,2,3-Trimethylenecyclohexane: 2, Observation of Tetrabutylammonium Fluorodithioformate [R] . Koeplinger, K. A. 1987

机译：两种交叉共轭三烯的合成和二聚反应：3-亚甲基-1,4-戊二烯和1,2,3-三亚甲基环己烷：2，四丁基氟代硫代甲酸铵的观察

CONVENIENT SYNTHESIS OF 1,3,6-TRIENE SYSTEMS THROUGH ALKYLATION OF 3-METHYL-3-SULFOLENE

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