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Synthesis and electrochemical properties of novel oligo-TTF donors

机译:新型低聚TTF供体的合成与电化学性能

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摘要

A series of novel oligomeric electron donors containing two to six TTF cores (5-11) were synthesized. The structures were assigned by NMR spectroscopy, infrared spectrometry and mass spectra. Their elec-trochemical properties were investigated by cyclic voltammetry (CV). All the compounds exhibited two pairs of nearly ideal redox waves. No distinct shift of the redox potentials was observed when TTF units increased.
机译:合成了一系列新颖的包含2至6个TTF核(5-11)的低聚物电子供体。通过NMR光谱,红外光谱和质谱对结构进行分配。通过循环伏安法(CV)研究了它们的电化学性质。所有化合物均表现出两对接近理想的氧化还原波。当TTF单位增加时,没有观察到氧化还原电位的明显变化。

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