Studies on Picrate. VIII. Crystal and Molecular Structures of Aromatic Amine Picrates: Aniline, N-Methylaniline, N,N-Dimethylaniline and o~-, m- and p-Phenylenediamine Picrates

Hiroaki Takayanagi; Toshitsugu Kai; Shin-ichi Yamaguchi; Kazuyoshi Tareda; Motoaki Goto

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Studies on Picrate. VIII. Crystal and Molecular Structures of Aromatic Amine Picrates: Aniline, N-Methylaniline, N,N-Dimethylaniline and o~-, m- and p-Phenylenediamine Picrates

机译：苦味研究。八。芳香胺型苦味酸盐的晶体和分子结构：苯胺，N-甲基苯胺，N，N-二甲基苯胺和邻，间和对苯二胺苦味酸盐

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The crystal and molecular structures of the title compounds have been elucidated by X-ray structure analysis. All compounds are formed through ionic and hydrogen bondings in the crystal state. The picrates of /V-methylaniline and m-phenylenediamine have additional n-bondings. The picrates are 1:1 complexes except for o-phenylenediamine picrate, in which the picrate consists of one o-phenylenediamine and two picric acid molecules.

机译：通过X射线结构分析已经阐明了标题化合物的晶体和分子结构。所有化合物都是通过处于结晶态的离子键和氢键形成的。 / V-甲基苯胺和间苯二胺的苦味酸酯具有另外的n键。苦味酸盐是1：1的络合物，除了邻苯二胺苦味酸盐外，其中苦味酚由一个邻苯二胺和两个苦味酸分子组成。

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《Chemical and Pharmaceutical Bulletin》 |1996年第12期|共6页
作者
Hiroaki Takayanagi; Toshitsugu Kai; Shin-ichi Yamaguchi; Kazuyoshi Tareda; Motoaki Goto;
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正文语种 eng
中图分类药学;
关键词
picrate; aromatic amine; crystal structure; X-ray analysis;

机译：苦味精;芳香胺;晶体结构;X射线分析;

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1. Studies on Picrate. VIII. Crystal and Molecular Structures of Aromatic Amine Picrates: Aniline, N-Methylaniline, N,N-Dimethylaniline and o~-, m- and p-Phenylenediamine Picrates [J] . Hiroaki Takayanagi, Toshitsugu Kai, Shin-ichi Yamaguchi, Chemical and Pharmaceutical Bulletin . 1996,第12期

机译：苦味研究。八。芳香胺型苦味酸盐的晶体和分子结构：苯胺，N-甲基苯胺，N，N-二甲基苯胺和邻，间和对苯二胺苦味酸盐
2. Studies on Picrates. IX. Crystal Structures of o-Xylene and p-Xylene Picrates [J] . Motoaki Goto, Yumiko Osa, Kazuyoshi Takeda, Chemical and Pharmaceutical Bulletin . 1998,第10期

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3. Studies on amino acid picrates: Crystal growth, structure and characterization of a new nonlinear optical material L-isoleucinium picrate [J] . G. Ramasamy, Subbiah Meenakshisundaram Optik: Zeitschrift fur Licht- und Elektronenoptik: = Journal for Light-and Electronoptic . 2014,第16期

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机译：2-氨基-N-（2-羟基-3-甲氧基亚苄基）苯胺的合成，NMR光谱和晶体结构研究
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机译：一，抗老剂麻油酮的晶体和分子结构；二。两种嘧啶酮的晶体和分子结构；三，邻苯二甲酸酐的晶体和分子结构； IV。头孢洛辛酯，强效抗癌剂的侧链合成研究。
6. Hydrogen bonding in the crystal structure of the molecular salt of pyrazole–pyrazolium picrate [O] . Ping Su, Xue-gang Song, Ren-qiang Sun, 2016

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7. Crystal Structure of N(6),N(6)-Dimethyladeninium Picrate. [O] . Tor Dahl, Ole Hammerich, Vernon D. Parker, 1986

机译：N（6），N（6）-dimethyladeniniumium的晶体结构。

Studies on Picrate. VIII. Crystal and Molecular Structures of Aromatic Amine Picrates: Aniline, N-Methylaniline, N,N-Dimethylaniline and o~-, m- and p-Phenylenediamine Picrates

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