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首页> 外文期刊>Biomaterials >Effect of chemical structure on degree of conversion in light-cured dimethacrylate-based dental resins.
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Effect of chemical structure on degree of conversion in light-cured dimethacrylate-based dental resins.

机译:化学结构对光固化的二甲基丙烯酸酯基牙科树脂转化率的影响。

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摘要

In this work the room-temperature photopolymerization of Bis-GMA, Bis-EMA, urethane dimethacrylate (UDMA) and triethylene glycol dimethacrylate (TEGDMA) induced by camphoroquinone/N,N-dimethylaminoethyl methacrylate, as photo-initiator system, was followed by FT-IR. The results obtained were then fitted by a non-linear least square method to a rational function, which permitted the accurate calculation of the limiting degree of conversion. The latter was found to increase in the order Bis-GMA < Bis-EMA < UDMA < TEGDMA. This trend is discussed in connection with the chemical structure of dimethacrylates. The photopolymerization of mixtures of Bis-GMA/TEGDMA, Bis-GMA/UDMA and Bis-GMA/Bis-EMA showed a good linear relationship of degree of conversion with the mole fraction of Bis-GMA and in the case of the first pair also with the Tg of the initial monomer mixture.
机译:在这项工作中,以樟脑醌/甲基丙烯酸N,N-二甲基氨基乙酯为引发剂,在室温下对Bis-GMA,Bis-EMA,氨基甲酸乙酯二甲基丙烯酸酯(UDMA)和三乙二醇二甲基丙烯酸酯(TEGDMA)进行室温光聚合,然后进行FT -IR。然后将获得的结果通过非线性最小二乘法拟合为有理函数,从而可以精确计算极限转化率。发现后者以Bis-GMA

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