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首页> 外文期刊>Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry >Synthesis, Physicochemical and Electrochemical Studies on Mn(II), Co(II), Ni(II), and Cu(II) Complexes with an N-Donor Tetradentate (N4) Macrocycle Ligand Derived from Ethyl Cinnamate
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Synthesis, Physicochemical and Electrochemical Studies on Mn(II), Co(II), Ni(II), and Cu(II) Complexes with an N-Donor Tetradentate (N4) Macrocycle Ligand Derived from Ethyl Cinnamate

机译:肉桂酸乙酯衍生的N-供体四齿(N4)大环配体的Mn(II),Co(II),Ni(II)和Cu(II)配合物的合成,物理化学和电化学研究

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摘要

Manganese(II), cobalt(Il), nickel(II), and copper(II) complexes with a new tetradentate ligand, l,3,7,9-tetraaza-4,10-diketo-6,12-diphenyl-2,8-dithiocyclododecane (L), were synthesized and characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, mass, ~1H NMR, IR, electronic, EPR spectral and cyclic voltammetric studies. On the basis of the IR, electronic, and EPR spectral studies, an octahedral geometry has been assigned for the Mn(II) and Co(II) complexes, a square-planar one for the Ni(II) and a tetragonal one for the Cu(II) complexes.
机译:锰(II),钴(II),镍(II)和铜(II)与新的四齿配位体1,3,7,9-tetraaza-4,10-diketo-6,12-diphenyl-2的配合物合成了8,8-二硫代环十二烷(L),并通过元素分析,摩尔电导测量,磁化率测量,质量,〜1H NMR,IR,电子,EPR光谱和循环伏安法研究对其进行了表征。根据红外,电子和EPR光谱研究,已为Mn(II)和Co(II)配合物分配了八面体几何形状,为Ni(II)分配了正方形平面的构面,并为四角形Cu(II)配合物。

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