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首页> 外文期刊>Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry >Construction of two different topological frameworks of Mn(II) coordination polymers based on the dicarboxylate and imidazole-containing ligands
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Construction of two different topological frameworks of Mn(II) coordination polymers based on the dicarboxylate and imidazole-containing ligands

机译:基于二羧酸盐和含咪唑配体的Mn(II)配位聚合物的两种不同拓扑框架的构建

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摘要

Two new Mn(II) coordination polymers, {[Mn(5-CH_3-ip)(bib)] ·2H_2O}_n (1) and [Mn (5-CH_3- ip)(bib)_(0.5)]_n (2) (5-CH_3-ip = 5-Methyl-1,3-benzenedicarboxylic acid bib = 1,4-bis(imidazol-1-yl) benzene), have been synthesized and characterized by elemental analysis, IR, and X-ray diffraction. Complex 1 shows a 2D layer structure. Complex 2 is a 3D structure (3,7)-connected topology with a Sch?fli symbol of (6~(20).8). (6~3). The topology has been well controlled by pH value.
机译:两种新的Mn(II)配位聚合物{[Mn(5-CH_3-ip)(bib)]·2H_2O} _n(1)和[Mn(5-CH_3- ip)(bib)_(0.5)] _ n( 2)已合成(5-CH_3-ip = 5-甲基-1,3-苯二甲酸bib = 1,4-双(咪唑-1-基)苯),并通过元素分析,IR和X-进行了表征射线衍射。复合体1显示2D层结构。复合体2是3D结构(3,7)连接的拓扑,其Schffli符号为(6〜(20).8)。 (6〜3)。通过pH值可以很好地控制拓扑结构。

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