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A lumped kinetic model for heavy oil catalytic cracking FDFCC process

机译:重油催化裂化FDFCC过程的集总动力学模型

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摘要

Based on the reaction mechanisms and the characteristics of flexible dual-riser fluid catalytic cracking (FDFCC) process, the reaction networks of 10 lumps for heavy oil and seven lumps for gasoline were put forward. The cracking reactions of resin and asphaltene into gasoline and gases in heavy oil riser reactor were considered as second-order ones while the other reactions were described as first-order ones. The kinetic parameters indicate good consistence with the reaction rules of heavy oil catalytic cracking. The relative errors between calculated values and actual values of products are all less than 4%, which shows the reliability of the models.
机译:基于柔性双管流化床催化裂化的反应机理和特点,提出了重油10块,汽油7块的反应网络。树脂和沥青质在重油提升管反应器中裂化为汽油和气体的反应被认为是二级反应,而其他反应则被描述为一级反应。动力学参数表明与重油催化裂化的反应规律具有良好的一致性。产品计算值与实际值之间的相对误差均小于4%,说明了模型的可靠性。

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