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首页> 外文期刊>Phase Transitions >Characterization of organic-inorganic hybrid layered perovskite and intercalated compound (n-C12H25NH3)(2)ZnCl4
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Characterization of organic-inorganic hybrid layered perovskite and intercalated compound (n-C12H25NH3)(2)ZnCl4

机译：有机-无机杂化层状钙钛矿和插层化合物（n-C12H25NH3）（2）ZnCl4的表征

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摘要

We report on some electrical properties and solid-solid phase transitions of organic-inorganic hybrid layered halide perovskite and intercalated compound (n-C12H25NH3)(2)ZnCl4 which is one member of the long-chain compounds of the series (n-CnH2n+1NH3)(2,)(n = 8-18). The complex dielectric permittivity epsilon*(omega,T) and the ac conductivity sigma (omega,T) were measured as functions of temperature 100 K < T < 390 K and frequency 5 kHz < f < 100 kHz. Moreover, the differential scanning calorimetery and the differential thermal analysis thermograms were performed. The analysis of our data confirms the existence of a structural phase transition at T approximate to (362 +/- 2) K, where the compound changes its state from intercalation to non-intercalation with a drastic increase in the c-axis by about 16.4%.
机译：我们报告了有机-无机杂化层状钙钛矿和嵌入的化合物（n-C12H25NH3）（2）ZnCl4的一些电学性质和固-固相变，该化合物是该系列长链化合物（n-CnH2n + 1NH3）（2，）（n = 8-18）。测量的复介电常数ε*（ωT）和交流电导率σ（ωT）是温度100 K

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