Dielectric, thermal and Raman spectroscopy studies of lead-free (Na0.5Bi0.5)(1-x)SrxTiO3 (x=0, 0.04 and 0.06) ceramics

Suchanicz J.; Bovtun V.; Dutkiewicz E. M.; Konieczny K.; Sitko D.; Kluczewska K.; Wajda A.; Kalvane A.; Sternberg A.

首页> 外文期刊>Phase Transitions >Dielectric, thermal and Raman spectroscopy studies of lead-free (Na0.5Bi0.5)(1-x)SrxTiO3 (x=0, 0.04 and 0.06) ceramics

【24h】

Dielectric, thermal and Raman spectroscopy studies of lead-free (Na0.5Bi0.5)(1-x)SrxTiO3 (x=0, 0.04 and 0.06) ceramics

机译：无铅（Na0.5Bi0.5）（1-x）SrxTiO3（x = 0、0.04和0.06）陶瓷的介电，热和拉曼光谱研究

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Lead-free (Na0.5Bi0.5)(1-x)SrxTiO3 (x = 0, 0.04 and 0.06) ceramics with relative densities above 97% were prepared by solid-state synthesis process. Their dielectric, thermal and Raman properties were studied. X-ray diffraction analysis shows perovskite structure with rhombohedral symmetry at room temperature. Sr doping of Na0.5Bi0.5TiO3 (NBT) results in an increase of the dielectric permittivity, diffusing of the permittivity maximum and its shift toward lower temperatures. The temperature of the rhombohedral-tetragonal phase transition indicated by the differential scanning calorimetry (DSC) peak and relaxational dielectric anomaly near the depolarization temperature are also shifted toward lower temperatures. The observed increase and broadening of the permittivity maximum, enhancement of the dielectric relaxation near the depolarization temperature, broadening of the DSC anomaly related to the rhombohedral-tetragonal phase transition and broadening of the Raman bands with increasing Sr content are attributed to the increase of the degree of cationic disorder and evident enhancement of the relaxor-like features in NBT-xST. This enhancement could play a positive role in the improvement of the piezoelectric performance of NBT-based ceramics.

机译：通过固态合成工艺制备了相对密度大于97％的无铅（Na0.5Bi0.5）（1-x）SrxTiO3（x = 0、0.04和0.06）陶瓷。研究了它们的介电，热和拉曼性能。 X射线衍射分析显示钙钛矿结构在室温下具有菱面体对称性。 Sr掺杂的Na0.5Bi0.5TiO3（NBT）导致介电常数的增加，介电常数最大值的扩散及其向较低温度的偏移。由差示扫描量热法（DSC）峰指示的菱形-四边形相变的温度和去极化温度附近的弛豫介电异常也向较低温度移动。观察到的介电常数最大值的增加和扩展，在去极化温度附近的介电弛豫的增强，与菱形-四边形相变有关的DSC异常的扩展以及随着Sr含量增加的拉曼谱带的扩展归因于阳离子障碍的程度和NBT-xST中类似松弛子的特征的明显增强。这种增强作用可以在改善NBT基陶瓷的压电性能中发挥积极作用。

著录项

来源
《Phase Transitions》 |2016年第8期|共7页
作者
Suchanicz J.; Bovtun V.; Dutkiewicz E. M.; Konieczny K.; Sitko D.; Kluczewska K.; Wajda A.; Kalvane A.; Sternberg A.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类物理学;
关键词
Thermal properties; structural properties; ferroelectric properties; dielectric properties;

机译：热性能;结构性能;铁电性能;介电性能;

相似文献

外文文献
中文文献
专利

1. Dielectric, thermal and Raman spectroscopy studies of lead-free (Na0.5Bi0.5)(1-x)SrxTiO3 (x=0, 0.04 and 0.06) ceramics [J] . Suchanicz J., Bovtun V., Dutkiewicz E. M., Phase Transitions . 2016,第7a8期

机译：无铅（Na0.5Bi0.5）（1-x）SrxTiO3（x = 0、0.04和0.06）陶瓷的介电，热和拉曼光谱研究
2. Dielectric and impedance spectroscopy analysis of lead-free (1-x) (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O-3-xBaTiO(3) ceramics [J] . Liu Yang, Du Yi, Cheng Chuanbing, CERAMICS INTERNATIONAL . 2019,第10期

机译：无铅（1-X）的介电和阻抗光谱分析（K0.4440.52LI0.04）（NB0.86TA0.10SB0.04）O-3-Xbatio（3）陶瓷
3. Impedance spectroscopy studies on (Na0.5Bi0.5)(0.94)Ba0.06TiO3+0.3 wt% Sm2O3+0.25 wt% LiF lead-free piezoelectric ceramics [J] . Zidi N., Chaouchi A., DAstorg S., Bulletin of Materials Science . 2015,第3期

机译：（Na0.5Bi0.5）（0.94）Ba0.06TiO3 + 0.3 wt％Sm2O3 + 0.25 wt％LiF无铅压电陶瓷的阻抗谱研究
4. Structural, dielectric, piezoelectric and ferroelectric properties of lead-free (1-x)Na_(0.5)Bi_(0.5)TiO_3-xBaTiO_3 (x=0.00, 0.04, 0.06, 0.08) ceramic [C] . Rajesh Narayana Perumal, Venkatraj Athikesavan DAE Solid State Physics Symposium . 2019

机译：无铅（1-x）Na_（0.5）Bi_（0.5）TiO_3-XbatiO_3（x = 0.00,0.04,0.06,0.08）陶瓷的结构，电介质，压电和铁电性能。（0.5）TiO_3-xbatio_3（x = 0.04,0.06,0.08）陶瓷
5. Novel lead-free piezoelectric ceramics in the solid solution (1-x) bismuth iron oxide-barium titanate. [D] . Leontsev, Serhiy. 2011

机译：固溶（1-x）氧化铁铋-钛酸钡中的新型无铅压电陶瓷。
6. Piezoelectric Ceramics of the (1 − x)Bi0.50Na0.50TiO3–xBa0.90Ca0.10TiO3 Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary a Case Study for x = 0.06 [O] . Rodrigo Vivar-Ocampo, Lorena Pardo, David Ávila, 2017

机译：（1- x）Bi0.50Na0.50TiO3–xBa0.90Ca0.10TiO3的无铅固溶体的压电陶瓷：趋同相边界的化学位移x = 0.06的案例研究
7. Structure and dielectric studies of (1-x)Ba0.06(Na0.5Bi0.5)0.94TiO3- xBa(Fe0.5Nb0.5)O3 lead-free ceramics [O] . Sumit Roy, Satyendra Singh, Sanat Mukherjee, 2019

机译：（1-x）Ba0.06（Na0.5bi0.5）的结构和介电研究0.94tio3- XBA（Fe0.5NB0.5）O3无铅陶瓷

Dielectric, thermal and Raman spectroscopy studies of lead-free (Na0.5Bi0.5)(1-x)SrxTiO3 (x=0, 0.04 and 0.06) ceramics

摘要

著录项

相似文献

相关主题

期刊订阅