Development of the synthesis methods of polyheterophosphacyclanes with endocyclic P-C bond on the basis of functionalized alkylphosphonates (-phosphinates)

Pudovik MA; Khailova NA; Bagautdinova RK; Terenteva SA; Kibardina LK; Kataeva ON; Alfonsov VA

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Development of the synthesis methods of polyheterophosphacyclanes with endocyclic P-C bond on the basis of functionalized alkylphosphonates (-phosphinates)

机译：在官能化的烷基膦酸酯（-次膦酸酯）的基础上开发具有内环P-C键的聚杂磷酰基环的合成方法

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We developed a new approach to the synthesis of saturated and unsaturated phosphoruselementocontaining heterocycles was developed; we based it on the addition reactions of various proton nucleophiles (amines, sitylamines, alcoholes, mercaptanes, aminoalkylphosphonates, phosphines, CH-acides, etc.) to the halogen-methylphosphonylated isocyanates or isothiocyanates. Intermediate compounds of these reactions (phosphorylated ureas, thioureas, urethanes, thiouretanes, acylamides, etc.) are easily transformed into phosphorus containing cyclic structures.

机译：我们开发了一种合成饱和和不饱和含磷元素杂环的新方法。我们基于各种质子亲核试剂（胺，谷氨酰胺，醇，硫醇，氨基烷基膦酸酯，膦，CH-酸等）与卤素-甲基膦酰基化的异氰酸酯或异硫氰酸酯的加成反应为基础。这些反应的中间化合物（磷酸化的脲，硫脲，氨基甲酸酯，硫脲，酰酰胺等）很容易转化为含磷的环状结构。

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《Phosphorus, Sulfur, and Silicon and the Related Elements》 |2008年第3期|共3页
作者
Pudovik MA; Khailova NA; Bagautdinova RK; Terenteva SA; Kibardina LK; Kataeva ON; Alfonsov VA;
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正文语种 eng
中图分类非金属元素及其化合物;
关键词
addition reactions; intramolecular cyclization; polyheterophosphacyclanes; posphorylated iso(thio)cyanates; proton nucleophiles;

机译：加成反应;分子内环化;多杂磷酰基团;磷酸化异（硫）氰酸酯;质子亲核体;

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1. Development of the synthesis methods of polyheterophosphacyclanes with endocyclic P-C bond on the basis of functionalized alkylphosphonates (-phosphinates) [J] . Pudovik MA, Khailova NA, Bagautdinova RK, Phosphorus, Sulfur, and Silicon and the Related Elements . 2008,第2a3期

机译：在官能化的烷基膦酸酯（-次膦酸酯）的基础上开发具有内环P-C键的聚杂磷酰基环的合成方法
2. Nucleophilic displacements in alkylphosphonates: P-O versus P-C bond cleavage. A combined DFT and experimental study [J] . Ashkenazi N., Chen R. Phosphorus, Sulfur, and Silicon and the Related Elements . 2013,第1a3期

机译：烷基膦酸酯中的亲核取代：P-O与P-C键裂解。 DFT与实验研究相结合
3. Synthesis, kinetics, and stereochemistry of P-C bond breaking and P-C bond making reactions: Ruthenium-arene binap chemistry [J] . Geldbach TJ., Bassetti M., Pregosin PS. Organometallics . 2001,第14期

机译：P-C键断裂和P-C键生成反应的合成，动力学和立体化学：钌-芳烃联苯化学
4. Building information systems development methods: synthesising from a basis in both theory and practice [C] . Fowler, D.C., Swatman, Software Engineering Conference, 1998. Proceedings. 1998 Australian . 1998

机译：建筑信息系统开发方法：从理论和实践的基础上综合
5. Rhodium Catalyzed Carbon-Hydrogen Bond Functionalization: Development of Methods and Applications in Organic Synthesis [D] . Tsai, Andy Siu-Chun 2011

机译：铑催化的碳氢键官能化：方法的发展和在有机合成中的应用
6. Recent Developments in Organophosphorus Flame Retardants Containing P-C Bond and Their Applications [O] . Sophie Wendels, Thiebault Chavez, Martin Bonnet, 2017

机译：含P-C键的有机磷阻燃剂及其应用的最新进展
7. Diversity Synthesis via C−H Bond Functionalization: Concept-Guided Development of New C-Arylation Methods for Imidazoles J. Am. Chem. Soc. 2003, 125, 10580−10585. [O] . Bengü Sezen, Dalibor Sames 2006

机译：通过C-H键官能化的多样性合成：咪唑新型C-芳基化方法的概念引导式发展J.是。化学。 SOC。 2003,125,10580-10585。
8. Twisted P-C Double Bond: Synthesis and Structure of a (Methylene)phosphine Fe(C0)4 Complex [R] . Neilson, R. H., Thoma, R. J., Vickovic, I., 1984

机译：扭曲的p-C双键：（亚甲基）膦Fe（C0）4配合物的合成和结构

Development of the synthesis methods of polyheterophosphacyclanes with endocyclic P-C bond on the basis of functionalized alkylphosphonates (-phosphinates)

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