Direct observation of molten matter formation in the hydrogen-implanted subsurface of palladium

S. Senda; F. Okuyama

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Direct observation of molten matter formation in the hydrogen-implanted subsurface of palladium

机译：直接观察钯氢注入下表面熔融物的形成

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Magmatic molten matter was previously shown to flow out from the polycrystalline Pd surface at temperatures far lower than the melting point of Pd, under bombardment by showering H^ ions. Cross-sectional transmission electron microscopy has now established that molten matter is generated in a narrow space within a microscopic crater beneath the surface. The matter is colloidal in structure with non-crystalline particles uniformly distributed therein, indicating that it was in a molten state during ion bombardment.

机译：先前已经证明，在通过喷入H 2离子轰击下，岩浆熔融物在远低于Pd熔点的温度下从多晶Pd表面流出。横截面透射电子显微镜现已确定，在表面下方的微观火山口内的狭窄空间中会产生熔融物质。该物质为胶体结构，具有均匀分布的非晶态颗粒，表明该物质在离子轰击过程中处于熔融状态。

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《Philosophical Magazine Letters》 |2004年第6期|共6页
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S. Senda; F. Okuyama;
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中图分类物理学;
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1. Direct observation of molten matter formation in the hydrogen-implanted subsurface of palladium [J] . S. Senda, F. Okuyama Philosophical Magazine Letters . 2004,第6期

机译：直接观察钯氢注入下表面熔融物的形成
2. Direct in Situ Observation and Analysis of the Formation of Palladium Nanocrystals with High-Index Facets [J] . Gao Wenpei, Hou Yusheng, Hood Zachary D., Nano letters . 2018,第11期

机译：直接原位观察和分析高折射率剖面钯纳米晶体
3. Synthesis and characterization in solution and in the solid State of the palladium aryl bromide complexes [Pd(Ar)Br{(S)-BINAP}]: formation of cyclopalladated complexes and direct observation of a C-N reductive elimination to form heterocycles [J] . Journal of the Brazilian Chemical Society . 2004,第1期

机译：钯和芳基溴化物配合物[Pd（Ar）Br {（S）-BINAP}]在溶液和固态下的合成和表征：形成环钯配合物并直接观察C-N还原消除形成杂环
4. Direct observation of deformation and solidification process of metallic molten dropleton to substrate by using high speed video camera system [C] . Sachio Oki Thermal Spray Connects: Explore its surfacing Potential! . 2005

机译：使用高速摄像机系统直接观察金属熔滴在基板上的变形和凝固过程
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Direct observation of grain growth from molten silicon formed by micro-thermal-plasma-jet irradiation [O] . Shohei Hayashi, Yuji Fujita, Takahiro Kamikura, -1

机译：直接观察由微热等离子体射流辐射形成的熔融硅中的晶粒长大
7. On the Mechanism of the Palladium(II)-Catalyzed Decarboxylative Olefination of Arene Carboxylic Acids. Crystallographic Characterization of Non-Phosphine Palladium(II) Intermediates and Observation of Their Stepwise Transformation in Heck-like Processes [O] . -1

机译：钯（II）的机理 - 丙烯羧酸催化脱羧烯烃。非膦钯（II）中间体的结晶表征及其在Heck样方法中逐步转化的观察

Direct observation of molten matter formation in the hydrogen-implanted subsurface of palladium

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