Self-diffusion in binary mixtures: The system benzene/cyclohexane at high pressures

Jacob AC.; Zeidler MD.

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Self-diffusion in binary mixtures: The system benzene/cyclohexane at high pressures

机译：二元混合物中的自扩散：高压下的苯/环己烷体系

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Pulsed-gradient spin-echo proton NMR measurements were performed on a 1 : 1 mixture of benzene and cyclohexane at pressures between ambient and 200 MPa and temperatures between 298 and 333 K. A high-pressure probe head was constructed for this purpose. Since the resolution was sufficient to differentiate between the protons of both components, it was possible to obtain the single self-diffusion coefficients for benzene and cyclohexane in the mixture. The results are discussed on the basis of different theories (Thorne-Enskog, Jacucci-McDonald, Enninghorst-Wayne-Zeidler) applicable to mixtures. [References: 26]

机译：脉冲梯度自旋回波质子NMR测量是在环境压力至200 MPa之间，温度298至333 K之间的情况下，对苯与环己烷的1：1混合物进行的。为此构建了一个高压探头。由于分辨率足以区分两种组分的质子，因此有可能获得混合物中苯和环己烷的单一自扩散系数。在适用于混合物的不同理论（Thorne-Enskog，Jacucci-McDonald，Enninghorst-Wayne-Zeidler）的基础上讨论了结果。 [参考：26]

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《Physical chemistry chemical physics: PCCP》 |2003年第3期|共5页
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Jacob AC.; Zeidler MD.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Hard-sphere fluid; Transport-properties; Mass density; Dependence; Liquids; Temperature; Tetramethylsilane; Nmr;

机译：硬球流体;传输特性;质量密度;依赖性;液体;温度;四甲基硅烷;Nmr;

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1. Self-diffusion in binary mixtures: The system benzene/cyclohexane at high pressures [J] . Jacob AC., Zeidler MD. Physical chemistry chemical physics: PCCP . 2003,第3期

机译：二元混合物中的自扩散：高压下的苯/环己烷体系
2. Vapor-Liquid Equilibrium Data for Binary Systems of N,N-Dimethylacetamide with Cyclohexene, Cyclohexane, and Benzene Separately at Atmospheric Pressure [J] . Mi Wanliang, Tong Ruixin, Hua Chao, Journal of Chemical and Engineering Data: the ACS Journal for Data . 2015,第11期

机译：N，N-二甲基乙酰胺与环己烯，环己烷和苯的二元体系在大气压下的汽液平衡数据
3. Total pressure and excess Gibbs energy for the ternary mixture di-isopropyl ether plus 1-propanol plus benzene and its corresponding binary systems at 313.15 K [J] . Villamanan RM, Chamorro CR, Villamanan MA, Fluid Phase Equilibria . 2006,第2期

机译：二异丙醚加1-丙醇加苯的三元混合物及其对应的二元体系的总压力和吉布斯能量的上限为313.15 K
4. EXPERIMENTAL DENSITIES AND EXCESS VOLUMES FOR THE BINARY MIXTURES BENZENE-TOLUENE, ACETONE-BENZENE AND ACETONE-TOLUENE AT VARIOUS TEMPERATURES AND ATMOSPHERIC PRESSURE. [C] . Horacio A. Duarte, Gautam R. Pullalarevu, Chirag Desai, AIChE National Meeting . 2009

机译：二元混合物的实验密度和过量体积苯 - 甲苯，丙酮 - 苯和丙酮 - 甲苯在各种温度和大气压下。
5. Vapor-liquid equilibria in the binary systems containing n-hexane, cyclohexane and benzene [D] . Li, Ida Pik-Choi -1

机译：包含正己烷，环己烷和苯的二元体系中的汽液平衡
6. SIGNIFICANT STRUCTURE THEORY OF BINARY LIQUID MIXTURES: CARBON TETRACHLORIDE AND CYCLOHEXANE [O] . Kai Liang, Henry Eyring, Ray P. Marchi 1964

机译：二元液体混合物的重要结构理论：四氯化碳和环己烷
7. Ultrasonic velocity in binary mixtures under high pressures and their thermodynamic properties II : binary mixtures for benzene-toluene and benzene-o-xylene [O] . Takagi Toshiharu 1978

机译：高压下二元混合物的超声速度及其热力学性质II：苯-甲苯和苯-邻二甲苯的二元混合物
8. The Thermodynamic Properties of Binary Aromatic Systems. Ii. Excess Enthalpies and Volumes of Benzene + Toluene and Toluene + Isomeric Xylene Mixtures at 25C. [R] . Murakami, S., Lam, V. T., Benson, G. C. 1969

机译：二元芳烃体系的热力学性质。二。过量的焓和体积的苯+甲苯和甲苯+异构二甲苯混合物在25℃下。

Self-diffusion in binary mixtures: The system benzene/cyclohexane at high pressures

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