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首页> 外文期刊>Philosophical magazine, B. Physics of condensed matter, electronic, optical, and magnetic properties >Electron spin resonance studies of the enhanced rotation and the fractional Debye-Stokes-Einstein law in polymeric liquid crystals
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Electron spin resonance studies of the enhanced rotation and the fractional Debye-Stokes-Einstein law in polymeric liquid crystals

机译:电子自旋共振研究聚合物液晶中增强旋转和分数德拜-斯托克斯-爱因斯坦定律

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摘要

We investigated the rotational dynamics of molecular tracers dissolved in a polymeric mesophase using two magnetic resonance spectroscopies. It is found that the coupling between the reorientation and the viscous flow is partial and well described by the fractional Debye-Stokes-Einstein law tau proportional to eta(xi) with 0 < xi less than or equal to 1, tau and eta being the rotational correlation times of the tracers and the viscosity respectively. [References: 26]
机译:我们使用两个磁共振波谱研究了溶解在聚合物中间相中的分子示踪剂的旋转动力学。发现重新定向和粘性流之间的耦合是部分的,并且可以通过分数Debye-Stokes-Einstein定律tau与eta(xi)成比例来很好地描述,其中0

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