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Fictive temperature and medium range order in silicate glasses: a relationship between heat capacity and boson peak

机译:硅酸盐玻璃的虚构温度和中间范围阶数:热容与玻色子峰之间的关系

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摘要

The comparison of the heat capacity excess C-p/T-3 and of the boson peak in several silicate glasses, grossular (Ca3Al2Si3O12), diopside (CaMgSi2O6), wollastonite (CaSiO3) and enstatite (MgSiO3) shows good quantitative agreement, demonstrating a common origin for both observations. The effects of different fictive temperatures T-F are also measured in both cases and show an increase in the density g(omega) of states with increasing T-F. It is concluded that quenching or annealing affects mainly the medium-range order of silicate glasses. [References: 10]
机译:几种硅酸盐玻璃,块状(Ca3Al2Si3O12),透辉石(CaMgSi2O6),硅灰石(CaSiO3)和顽辉石(MgSiO3)的热容过量Cp / T-3和玻色子峰的比较显示出良好的定量一致性,证明了其常见来源对于两个观察。在两种情况下,都测量了不同虚拟温度T-F的影响,并且显示了随着T-F的增加,状态密度g(ω)的增加。可以得出结论,淬火或退火主要影响硅酸盐玻璃的中间范围。 [参考:10]

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