Vis-UV fluorescence studies of fragments resulting from the relaxation of molecular core hole states

Coreno M; Kivimaki A; de Simone M; Garcia EM; Vall-Llosera G; Ruiz JA; Rachlew E; Stankiewicz M

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Vis-UV fluorescence studies of fragments resulting from the relaxation of molecular core hole states

机译：分子核孔态弛豫产生的碎片的Vis-UV荧光研究

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The absorption of soft x-ray radiation induces neutral and ionic core hole states in molecules. The relaxation of such states typically leads to a multi-step process, at the end of which photons in the visible and UV range can also be emitted from fragments. In this paper, we present results on Balmer and Lyman emission that originates from excited H atoms produced at the K-edge of the water, ammonia and methane molecules. Dissociation pathways leading to fluorescence emission are discussed.

机译：软X射线辐射的吸收会在分子中诱导中性和离子型核孔态。这种状态的松弛通常导致多步过程，在此过程的最后，可见光和紫外线范围内的光子也可以从碎片中发射出来。在本文中，我们介绍了Balmer和Lyman发射的结果，该结果源自在水，氨和甲烷分子的K边缘产生的激发H原子。讨论了导致荧光发射的解离途径。

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《Physica Scripta: An International Journal for Experimental and Theoretical Physics》 |2007年第3期|共6页
作者
Coreno M; Kivimaki A; de Simone M; Garcia EM; Vall-Llosera G; Ruiz JA; Rachlew E; Stankiewicz M;
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正文语种 eng
中图分类物理学;
关键词
K-SHELL EXCITATION; CH4; METHANE; H2O; SPECTROSCOPY; NH3; TRANSITIONS; AMMONIA; WATER; 1S;

机译：钾壳激发;CH4;甲烷;H2O;光谱学;NH3;转变;氨;水;1S;

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1. Vis-UV fluorescence studies of fragments resulting from the relaxation of molecular core hole states [J] . Coreno M, Kivimaki A, de Simone M, Physica Scripta: An International Journal for Experimental and Theoretical Physics . 2007,第3期

机译：分子核孔态弛豫产生的碎片的Vis-UV荧光研究
2. Ab initio fragment molecular orbital study of molecular interactions between liganded retinoid X receptor and its coactivator; Part II: Influence of mutations in transcriptional activation function 2 activating domain core on the molecular interactio [J] . Ito M, Fukuzawa K, Mochizuki Y, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第10期

机译：配体类维生素A X受体与其共激活剂之间分子相互作用的从头算片段分子轨道研究;第二部分：转录激活功能2激活域核心中的突变对分子相互作用的影响
3. Ab initio fragment molecular orbital study of molecular interactions between liganded retinoid X receptor and its coactivator; Part II: Influence of mutations in transcriptional activation function 2 activating domain core on the molecular interactio [J] . Ito M, Fukuzawa K, Mochizuki Y, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第10期

机译：配体类维生素A X受体与其共激活剂之间分子相互作用的从头算片段分子轨道研究;第二部分：转录激活功能2激活域核心中的突变对分子相互作用的影响
4. Accessing nano- to femtosecond molecular relaxation phenomena for fluorescence imaging through double-pulse saturation excitation [C] . G.J. Brakenhoff, Univ. of Amsterdam, Amsterdam, Three-Dimensional Microscopy: Image Acquisition and Processing IV . 1997

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5. Effects of nanoscale confinement and interfaces on the structural relaxation of amorphous polymers monitored at the molecular scale by fluorescence and dielectric spectroscopy. [D] . Priestley, Rodney Dewayne. 2008

机译：纳米级限制和界面对无定形聚合物结构弛豫的影响，通过荧光和介电谱在分子尺度上进行监测。
6. Protein fragment bimolecular fluorescence complementation analyses for the in vivo study of protein-protein interactions and cellular protein complex localizations [O] . Rainer Waadt, Kathrin Schlücking, Julian I. Schroeder, -1

机译：蛋白质片段双分子荧光互补分析用于蛋白质-蛋白质相互作用和细胞蛋白质复合物定位的体内研究
7. Comment on "Electron core-hole interaction and its induced ionic structural relaxation in molecular systems under x-ray irradiation [O] . Schreiber F., Gerlach A., Koch N., 2007

机译：评论“ X射线照射下分子系统中的电子核-空穴相互作用及其诱导的离子结构弛豫
8. Creation, Relaxation and Recombination of Highest Lying Core Holes in IonicCrystals [R] . Belsky, A. N., Kamenskikh, I. A., Mikhailin, V. V., 1995

机译：IonicCrystals中最高层核心孔的创建，松弛和重组

Vis-UV fluorescence studies of fragments resulting from the relaxation of molecular core hole states

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