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Latest findings on the dynamics of the simplest chemical reaction

机译:最简单的化学反应动力学的最新发现

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This paper focuses on recent progress in the understanding of the H+H-2 reaction and its isotopic variants. The detailed agreement between theory and experiment attained during the last years is emphasized and major experimental and theoretical advances are highlighted. The excellent description of most experimental findings, from state-resolved cross-sections to thermal rate constants, provided by the available quantum mechanical (QM) treatments, as well as the good overall behaviour of classical mechanics are underlined. Debated issues on short-lived complexes and delayed scattering, resonances and interferences, geometric-phase (GP) effects, or product rotational distributions are discussed. Finally, some prospects for future research on this prototypic system are presented.
机译:本文着重于对H + H-2反应及其同位素变体的了解的最新进展。强调了过去几年中理论与实验之间的详细协议,并强调了主要的实验和理论进展。强调了大多数实验发现的出色描述,从状态解析的横截面到热速率常数,都由可用的量子力学(QM)处理提供,并且经典力学的总体性能也得到了很好的体现。讨论了有关短寿命复合物和延迟散射,共振和干扰,几何相位(GP)效应或产物旋转分布的辩论性问题。最后,介绍了该原型系统未来研究的一些前景。

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