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首页> 外文期刊>Physica Scripta: An International Journal for Experimental and Theoretical Physics >Influence of gallium substitutions on the structure, dielectric and piezoelectric properties of BiScO_3–PbTiO_3 ceramics
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Influence of gallium substitutions on the structure, dielectric and piezoelectric properties of BiScO_3–PbTiO_3 ceramics

机译:镓取代对BiScO_3–PbTiO_3陶瓷结构,介电和压电性能的影响

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摘要

Ceramics with compositions close to the morphotropic boundary in the (1?x)Bi(Sc_(1?y)Ga_y)O_3–xPbTiO_3 system were prepared by the conventional solid-state reaction method. The influence of substituting Ga~(3+) cations for Sc~(3+) cations on the structural parameters and the dielectric and piezoelectric properties was studied. It was proved that variations in the relative content of the tetragonal and rhombohedral phases depended on the tolerance-factor t value determined by the B-cation substitutions. The highest values of the piezoelectric coefficient d_(33) were observed in the compositions with the largest proportion of the tetragonal phase.
机译:采用常规固相反应法制备了在(1?x)Bi(Sc_(1?y)Ga_y)O_3–xPbTiO_3体系中接近变质边界的陶瓷。研究了用Ga〜(3+)取代Sc〜(3+)阳离子对结构参数,介电和压电性能的影响。证明四方相和菱面体相的相对含量的变化取决于由B-阳离子取代确定的耐受因子t值。在具有最大比例的四方相的组合物中观察到压电系数d_(33)的最大值。

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