Monosolvation effects in chiral fluoroorganic compounds: an R2PI study

Giardini A; Rondino F; Paladini A; Hortal AR; Satta M; Speranza M; Piccirillo S

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Monosolvation effects in chiral fluoroorganic compounds: an R2PI study

机译：R2PI研究：手性氟有机化合物中的单溶剂作用

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Wavelength- and mass-selected resonant-enhanced two-photon ionization (R2PI) spectra of supersonically expanded (R)-1-phenyl-2,2,2-trifluoroethanol (FER) and its complexes with water, R- and S-2-aminobutane (A(R/S)) and R- and S-2-butanol (B-R/S) are reported and discussed in the light of ab initio calculations. The effects of the fluorine atoms in these systems have been evaluated by comparing the results with the vibronic and mass spectra of their nonfluorinated analogues, i.e. adducts with (R)-phenyl-1-ethanol (E-R).

机译：超音速膨胀的（R）-1-苯基-2,2,2-三氟乙醇（FER）及其与水，R-和S-2配合物的波长和质量选择的共振增强双光子电离（R2PI）光谱根据从头算的方法报道并讨论了-氨基丁烷（A（R / S））和R-和S-2-丁醇（BR / S）。氟原子在这些系统中的作用已通过将结果与其非氟化类似物（即与（R）-苯基-1-乙醇（E-R）的加成物）的振动光谱和质谱进行比较来评估。

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《Physica Scripta: An International Journal for Experimental and Theoretical Physics》 |2008年第5期|共6页
作者
Giardini A; Rondino F; Paladini A; Hortal AR; Satta M; Speranza M; Piccirillo S;
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正文语种 eng
中图分类物理学;
关键词
GAS-PHASE; SPECTROSCOPY; COMPLEXES; CLUSTERS; PHOTOIONIZATION; IONIZATION; MOLECULE;

机译：气相;光谱;络合物;团簇;光化;电离;分子;

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1. Monosolvation effects in chiral fluoroorganic compounds: an R2PI study [J] . Giardini A, Rondino F, Paladini A, Physica Scripta: An International Journal for Experimental and Theoretical Physics . 2008,第5期

机译：R2PI研究：手性氟有机化合物中的单溶剂作用
2. Catalytic asymmetric synthesis of chiral fluoroorganic compounds [J] . Iseki K. Tetrahedron . 1998,第46期

机译：手性氟有机化合物的催化不对称合成
3. Laser R2PI spectroscopic and mass spectrometric studies of chiral neurotransmitters [J] . A. Giardini, V. Marotta, A. Paladini, Applied Surface Science . 2007,第19期

机译：手性神经递质的激光R2PI光谱和质谱研究
4. Synthesis and Study on the Mechanism of a Novel Chiral Spiran Compound [C] . Zhuob, Bing Deng, Zhuobin Shang, International symposium on fine chemistry and functional polymers . 2000

机译：一种新型手性螺旋化合物机理的合成与研究
5. STUDIES IN ORGANOSULFUR CHEMISTRY. I. NUCLEAR MAGNETIC RESONANCE (PROTON, CARBON-13, OXYGEN-17 (1) J(C-H)) INVESTIGATIONS OF ORGANOSULFUR COMPOUNDS. II. MECHANISTIC STUDY OF PHASE TRANSFER CATALYZED REACTIONS OF DICHLOROCARBENE WITH SULFIDES AND SULFOXIDES. III. STUDIES DIRECTED TOWARD ASYMMETRIC SYNTHESIS USING CHIRAL PHASE TRANSFER CATALYSTS. [D] . DYER, JOHN COLLINS. 1980

机译：有机硫化学研究。 I.有机硫化合物的核磁共振（质子，碳13，氧17（1）J（C-H））研究。二。二氯卡宾与硫化物和硫化物的相转移催化反应的机理研究。三，使用手性相转移催化剂进行不对称合成的研究。
6. Steric effects on the enantiodiscrimination of diproline chiral stationary phases in the resolution of racemic compounds [O] . Zhi Dai, Guozhong Ye, Charles U. Pittman Jr., -1

机译：对偶氮手性固定阶段对外消旋化合物分辨率的依赖性异常的影响
7. Photochemical R2PI study of chirality and intermolecular forces in supersonic beam [O] . A. Giardini Guidoni, S. Piccirillo, D. Scuderi, 2001

机译：光子化学R2pI研究超声波束中的手性和分子间力
8. NEW ANALYTICAL METHOD FOR CALORIMETRIC STUDY OF HYDROGENATION OF SOME FLUOROORGANIC COMPOUNDS [R] . J. R. Lancher, A. Kianpour, J. D. Park 1955

机译：一种含氟化合物加氢量热法的新分析方法

Monosolvation effects in chiral fluoroorganic compounds: an R2PI study

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