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Optical properties of metallic and semiconducting single-wall carbon nanotubes

机译:金属和半导体单壁碳纳米管的光学性质

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Optical properties of high purity metallic and semiconducting single-wall carbon nanotubes (SWCNTs) were investigated from far infrared to ultraviolet by optical absorption spectroscopy. It was found that the metallic SWCNT thin film has larger infrared absorption intensity than the semiconducting one. Furthermore, little changes in the optical absorption spectrum and the DC sheet resistance against molecular physisorptions were revealed in the metallic SWCNTs thin film. The stability of the metallic SWCNTs results from their constant electronic density of state near the Fermi level. On the other hand, the existence of semiconducting SWCNTs in the films makes their infrared absorption intensity and the sheet resistance more sensitive to the adsorption of molecules mainly due to carrier doping. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
机译:通过光学吸收光谱法研究了从远红外到紫外光的高纯度金属和半导体单壁碳纳米管(SWCNT)的光学特性。已经发现,金属SWCNT薄膜具有比半导体薄膜更大的红外吸收强度。此外,在金属SWCNTs薄膜中,光吸收光谱和DC薄层电阻对分子物理吸附的变化很小。金属SWCNT的稳定性来自其在费米能级附近的恒定电子态密度。另一方面,由于薄膜中存在半导体SWCNT,这主要是由于载流子掺杂,使得它们的红外吸收强度和薄层电阻对分子的吸附更加敏感。 (C)2008 WILEY-VCH Verlag GmbH&Co.KGaA,Weinheim

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