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首页> 外文期刊>Physica status solidi, B. Basic research >New orthorhombic multiferroics R1-xYxMnO3 (R = Eu, Gd)
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New orthorhombic multiferroics R1-xYxMnO3 (R = Eu, Gd)

机译:新的正交各向异性多铁化合物R1-xYxMnO3(R = Eu,Gd)

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摘要

A tendency to form multiferroic states with a spatially modulated antiferromagnetic structure and electric polarization in pure orthorhombic manganites RMnO3 upon decreasing of the rare-earth ionic radii has been realized in single crystals of substituted compounds Eu1-xYxMnO3 (0.2 <= x <= 0.5) and Gd1-yYyMnO3 (0 <= y <= 0.2). While the parent pure and slightly substituted (x <= 0.1) Compounds exhibited a spontaneous transition from the incommensurate (IC) to the canted anti ferromagnetic (CAF) state at T-CA < T-N = 45-50 K, the transitions from IC to commensurate ferroelectric (C/FE) phase were observed at T-lock < T-N for x >= 0.3 and y >= 0.05 accompanied by dielectric anomalies. Various phase transitions were observed in magnetic fields up to 250 kOe along the a-, b-, c-axes by magnetization, magnetostriction and electric polarization measurements. The latter indicate the existence of a spontaneous electric polarization below T-lock. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
机译:在取代化合物Eu1-xYxMnO3(0.2 <= x <= 0.5)的单晶中,已经实现了随着稀土离子半径的减小,在纯正交锰矿RMnO3中形成具有空间调制反铁磁结构和电极化的多铁态的趋势。和Gd1-yYyMnO3(0 <= y <= 0.2)。在T-CA = 0.05的T-lock

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