Optical and electrical properties of oriented thin films of oligomer containing betaine-type moiety in side chain

Muzikante I; Fonavs E; Tokmakov A; Cepite D; Stiller B; Brehmer L; Neilands O

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Optical and electrical properties of oriented thin films of oligomer containing betaine-type moiety in side chain

机译：侧链中含有甜菜碱型部分的低聚物取向薄膜的光学和电学性质

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Non-linear optical and electrical properties of polymer films obtained by dipole orientation of active units are reported. Novel polar oligomer with N-(indan-1,3-dion-2-yl)pyridinium betaine (IPB) as a side group is studied. Orientation of polar groups in oligomer thin films causes an increase of the photo-induced change of surface potential on irradiation in the region of photo-induced electron transfer (PIET) where the IPB group exhibits a reversible change of the value and sign of the dipole moment. At longer wavelengths, the value of the surface potential of the oligomer may be determined by transport of photo-generated charge carriers.

机译：报道了通过活性单元的偶极取向获得的聚合物膜的非线性光学和电学性质。研究了以N-（茚满-1,3-二价-2-基）吡啶甜菜碱（IPB）为侧基的新型极性低聚物。低聚物薄膜中极性基团的取向导致在光致电子转移（PIET）区域中IPB基团表现出偶极子的值和符号可逆变化的区域中，在辐照时光致表面势的光致变化增加时刻。在更长的波长下，低聚物的表面电势值可以通过光生电荷载流子的传输来确定。

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《Physica status solidi, B. Basic research》 |2005年第4期|共4页
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Muzikante I; Fonavs E; Tokmakov A; Cepite D; Stiller B; Brehmer L; Neilands O;
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Optical and electrical properties of oriented thin films of oligomer containing betaine-type moiety in side chain

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