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首页> 外文期刊>Physica status solidi, B. Basic research >Covalently functionalized carbon nanotubes as macroinitiators for radical polymerization
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Covalently functionalized carbon nanotubes as macroinitiators for radical polymerization

机译:共价官能化的碳纳米管作为自由基聚合的大分子引发剂

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摘要

Single-walled carbon nanotubes were functionalized along their sidewalls with hydroxyalkyl groups using a radical addition scheme. These moieties were found to be active in the polymerization of acrylic acid from the surface of the nanotubes by a redox radical mechanism. The resulting polymerized nanotubes were analyzed by UV-Vis, XPS, Raman and SEM techniques. The composite material was found to be soluble in aqueous media (pH > 5) and polar organic solvents. The reported grafting technique is expected to be suitable for industrial production of modified carbon nanotubes.
机译:使用自由基加成方案将单壁碳纳米管沿其侧壁用羟烷基官能化。通过氧化还原自由基机理,发现这些部分在丙烯酸从纳米管表面的聚合中具有活性。通过UV-Vis,XPS,拉曼和SEM技术分析所得的聚合的纳米管。发现该复合材料可溶于水性介质(pH> 5)和极性有机溶剂中。预期已报道的接枝技术适用于改性碳纳米管的工业生产。

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