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首页> 外文期刊>Physica, A. Statistical mechanics and its applications >EFFECTS OF ENCOUNTERS ON PHASE SEPARATION DYNAMICS FROM DIFFUSION-CONTROLLED GROWTH TO COARSENING
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EFFECTS OF ENCOUNTERS ON PHASE SEPARATION DYNAMICS FROM DIFFUSION-CONTROLLED GROWTH TO COARSENING

机译:相遇对从扩散控制到粗化的相分离动力学的影响

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摘要

We investigate the dynamics of phase separations in quenched binary mixtures, such as binary alloys and polymer blends with low mobilities, at higher volume fractions. Computer simulations are performed using simple model equations in the presence of encounters of droplets. Four characteristic stages with three crossovers, including dynamical scaling behavior and temporal power laws, are found beyond a volume fraction of approximately 0.14, where each crossover is attributed to a transition from one growth mechanism to the other. The encounter effect is thus shown to strongly influence a transition from the diffusion-controlled (t(1/2)) Stage to the coarsening (t(1/3)) stage. A simple analytical argument for the simulation results is also presented. [References: 28]
机译:我们研究了在淬火的二元混合物(例如二元合金和低迁移率的聚合物共混物)中以较高的体积分数进行相分离的动力学。在遇到液滴的情况下,使用简单的模型方程式进行计算机模拟。发现具有三个交叉的四个特征阶段,包括动态缩放行为和时间幂定律,超过大约0.14的体积分数,其中每个交叉都归因于从一种生长机制到另一种生长机制的过渡。因此表明,相遇效应强烈影响从扩散控制(t(1/2))阶段到粗化(t(1/3))阶段的过渡。还为仿真结果提供了一个简单的分析论据。 [参考:28]

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