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Carbon monoxide oxidation over platinum: stable, oscillatory and quasi-chaotic regimes

机译:一氧化碳在铂上的氧化:稳定,振荡和准混沌状态

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摘要

We model the heterogeneously catalyzed oxidation of CO over a Pt surface. A phase diagram analysis is used to probe the several steady state regimes and their stability. We incorporate an experimentally observed 'slow' sub-oxide kinetic step, thereby generalizing a previously presented model. In agreement with experimental data, stable, oscillatory and quasi-chaotic regimes are obtained. Furthermore, the inclusion of the sub-oxide step yields a relaxation oscillation regime. (C) 1998 Elsevier Science B.V. All rights reserved. [References: 7]
机译:我们模拟在Pt表面上CO的异相催化氧化。相图分析用于探究几种稳态状态及其稳定性。我们纳入了实验观察到的“慢速”次氧化物动力学步骤,从而推广了先前提出的模型。与实验数据一致,获得了稳定的,振荡的和准混沌的状态。此外,包含低氧化物步骤会产生弛豫振荡状态。 (C)1998 Elsevier Science B.V.保留所有权利。 [参考:7]

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