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Crystalline electric field and Kondo energy scales in YbCu5-xAgx

机译:YbCu5-xAgx中的晶体电场和近藤能级

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The specific heat of LuCu5-xAgx reference samples was measured to reanalyse the heavy-fermion behaviour of the isostructural AuBe5-type cubic system YbCu5-xAgx with x = 0-1 which is a series of dense Kondo compounds whose characteristic temperature T-0 decreases as x decreases. For YbCu5-xAgx, the gamma-value increases from 210 mJ/mol K-2 for x = 1.0 to 550 mJ/mol K-2 for x = 0.0. The analysis of the magnetic susceptibility and of the magnetic contribution to the specific heat in terms of Coqblin-Schrieffer (CS) model reveals a significant reduction of the effective ground state degeneracy: While YbCu4Ag is well described by the CS model with J =(1)/(2) and T-0 = 150 K, one has to consider a crystalline electric field splitting of the Yb3+ ground state multiplet with an 2 energy scale of the order of 80 K and a Kondo contribution corresponding to the CS model with J = (3)/(2) and T-0 similar to 30 K in the case of YbCu5, i.e. there is a cross-2 over of the characteristic energy scales of the Kondo interaction and of the CEF splitting within the series Yb(Cu, Ag)(5) (C) 2002 Elsevier Science B.V. All rights reserved. [References: 15]
机译:测量了LuCu5-xAgx参考样品的比热,以重新分析x = 0-1的等结构AuBe5型立方体系YbCu5-xAgx的重费米行为,这是一系列稠密的近藤化合物,其特征温度T-0降低随着x的减少。对于YbCu5-xAgx,对于x = 1.0,伽马值从210 mJ / mol K-2增加到对于x = 0.0,550 mJ / mol K-2。根据Coqblin-Schrieffer(CS)模型对磁化率和磁对比热的影响分析表明,有效基态简并性显着降低:而CS模型很好地描述了YbCu4Ag,其中J =(1 )/(2)且T-0 = 150 K,则必须考虑Yb3 +基态多重态的晶体电场分裂,其2能级为80 K,并且Kondo贡献对应于J的CS模型。 =(3)/(2)且T-0在YbCu5的情况下类似于30 K,即在Yb(Cu ,Ag)(5)(C)2002 Elsevier Science BV保留所有权利。 [参考:15]

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