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首页> 外文期刊>Physica, C. Superconductivity and its applications >Structural and superconducting properties of La2CuO4+delta chemically oxidized by NaClO
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Structural and superconducting properties of La2CuO4+delta chemically oxidized by NaClO

机译:NaClO化学氧化的La2CuO4 +δ的结构和超导性能

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A series of La2CuO4+0 samples chemically oxidized in NaClO aqueous solution at room temperature with different oxidation time of 2-120 h have been prepared. The X-ray powder diffraction analyses indicate that all the oxidized samples are orthorhombic and single phase, and show an enhanced orthorhombic distortion with the oxidation time, compared with that of the as-prepared sample. The magnetic susceptibility measurements indicate that all the oxidized samples are bulk superconductors with an onset transition temperature at 45 K. The excess oxygen contents of the oxidized samples determined by iodometric titration increase with the oxidation time, which versus the oxidation time obeys the law of the second order exponential decay. The grain size observed by scanning electron microscopy has no obvious changes for the sample before and after oxidation. All the results indicate that NaClO is indeed an efficient oxidizing agent for La2CuO4. (C) 2001 Elsevier Science B.V. All rights reserved. [References: 24]
机译:制备了一系列在室温下在NaClO水溶液中化学氧化的La2CuO4 + 0样品,不同的氧化时间为2-120 h。 X射线粉末衍射分析表明,所有氧化的样品均为正交晶且为单相,并且与制备后的样品相比,氧化时间显示正交晶畸变增强。磁化率测量表明,所有氧化的样品都是块状超导体,其起始转变温度为45K。通过碘量滴定法测定的氧化样品中的过量氧含量随氧化时间的增加而增加,而氧化时间与氧化时间的服从定律有关。二阶指数衰减。通过扫描电子显微镜观察到的晶粒尺寸在氧化之前和之后没有明显的变化。所有结果表明,NaClO确实是La2CuO4的有效氧化剂。 (C)2001 Elsevier Science B.V.保留所有权利。 [参考:24]

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