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Potential Molecular Wires by an Iterative Divergent/Convergent Approach. Doublingof Molecular Length at Each Iteration

机译：通过迭代发散/收敛方法的潜在分子导线。每次迭代时分子长度加倍

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We have devised an iterative convergent/divergent approach to conjugatedoligomers that might serve as molecular wires. The molecular length doubles with each iteration. The systems prepared are completely monodispersed and based upon oligo(thiophene-ethynylene)s (1) and oligo(phenylene-ethynylene)s at 100 A and 128 A long, respectively. The optical and SEC properties will be discussed. Methods are outlined to attach end groups that might serve as molecular alligator clips.

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作者
Pearson, D. L.; Schumm, J. S.; Jones, L.; Tour, J. M.;
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年度 1994
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总页数 9
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Oligomers; Molecular electronics; Iterations; Length; Thiophenes; Wire; Synthesis(Chemistry); Optical properties; Chemical bonds; Polymers; Molecular structure; Electrical conductivity;

机译：低聚物;分子电子学;迭代;长度;噻吩;线;合成（化学）;光学性质;化学键;聚合物;分子结构;电导率;

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专利

1. Potential Molecular Wires by an Iterative Doubling Approach. Doubling of Molecular Length at Each Iteration [J] . Darren L. Pearson, James M. Tour Polymer Preprints . 1995,第2期

机译：潜在的分子线通过迭代加倍方法。每次迭代时分子长度加倍
2. Precise Synthesis of Molecularly Defined Oligomers and Polymers by Orthogonal Iterative Divergent/Convergent Approaches [J] . Sandra Binauld, Denis Damiron, Luke A. Connal, Macromolecular Rapid Communications . 2011,第2期

机译：正交迭代发散/收敛方法精确合成分子定义的低聚物和聚合物
3. Precise synthesis of molecularly defined oligomers and polymers by orthogonal iterative divergent/convergent approaches [J] . Binauld S., Damiron D., Connal L.A., Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation . 2011,第2期

机译：通过正交迭代发散/收敛方法精确合成分子定义的低聚物和聚合物
4. Monotonic convergent iterative learning controller design with iteration varying model uncertainty [C] . Hyo-Sung Ahn, Moore, K.L., . 2005

机译：迭代不确定模型的单调收敛迭代学习控制器设计。
5. Incorporation of Molecular Diagnostics into Medical Laboratory Science Curriculum: Clinical Facilities Expectations. An Asynchronous, Iterative, Online Delphi Study [D] . Kraj, Barbara 2015

机译：将分子诊断学纳入医学实验室科学课程：临床设施的期望。异步，迭代的在线Delphi研究
6. Molecular basis of methylation and chain-length programming in a fungal iterative highly reducing polyketide synthase [O] . Xiao-Long Yang, Steffen Friedrich, Sen Yin, 2019

机译：真菌迭代高还原性聚酮化合物合酶中甲基化和链长编程的分子基础
7. Convergent Synthesis of 10 nm Aryleneethynylene Molecular Wires by an Iterative Regioselective Deprotection/Sonogashira Coupling Protocol [O] . -1

机译：通过迭代区域选择性脱保护/ Sonogashira偶联方案收敛合成10nm芳基乙烯分子线

Potential Molecular Wires by an Iterative Divergent/Convergent Approach. Doublingof Molecular Length at Each Iteration

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