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EQCM Measurements: Redox-Induced Changes in Solvent and Ion Content in AnchoredRedox Monolayers of Organosulfur Compounds and Their Electrocatalysis on Gold Electrodes

机译：EQCm测量：氧化还原诱导的有机硫化合物的anchoredRedox单层中溶剂和离子含量的变化及其对金电极的电催化作用

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This project involved the use of the Electrochemical Quartz Crystal Microbalance(EQCM) to detect redox-induced changes in ion and solvent content in disulfide and thiol anchored monolayers. The EQCM will also be used to detect the monolayers' electrocatalytic effects on various organometallic cations. The EQCM simultaneously measures the current response to changes in potential with the corresponding frequency response induced by those changes. Use is made of organosulfur compounds as precursors for attachment of organometallic and organic redox couples. Several organometallic disulfides (e.g. cobalticinium and ferrocene derivatives) and organic amphiphilic thiols (e.g. viologen derivatives) have been synthesized and chemisorbed onto gold EQCMs. (JES)

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作者
De Long, H. C.;
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年度 1990
页码
总页数 149
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Catalysis; Coupling(Interaction); Electrocatalysts; Gold; Oxidation reductionreactions; Cations; Chemical derivatives; Electrochemistry; Electrodes; Ferrocenes; Frequency response; Layers; Organic sulfur compounds; Organometallic compounds; Response; Thio;

机译：催化;偶联（相互作用）;电催化剂;金;氧化还原反应;阳离子;化学衍生物;电化学;电极;二茂铁;频率响应;层;有机硫化合物;有机金属化合物;响应;硫代;

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专利

1. REDOX-INDUCED ORIENTATION CHANGE OF A SELF-ASSEMBLED MONOLAYER OF 11-FERROCENYL-1-UNDECANETHIOL ON A GOLD ELECTRODE STUDIED BY IN SITU FT-IRRAS [J] . Ye S., Uosaki K., Sato Y. Langmuir: The ACS Journal of Surfaces and Colloids . 1997,第12期

机译：原位红外光谱法研究金电极上自组装的11-二茂铁-1-十一碳四烯醇单分子膜的氧化还原取向变化
2. Coverage dependent behavior of redox reaction induced structure change and mass transport at an 11-ferrocenyl-1-undecanethiol self-assembled monolayer on a gold electrode studied by an in situ IRRAS-EQCM combined system [J] . Shen Ye, Toshio Haba, Yukari Sato, Physical chemistry chemical physics: PCCP . 1999,第15期

机译：原位IRRAS-EQCM组合系统研究金电极上11-二茂铁基-1-十一烷硫醇自组装单层上氧化还原反应诱导的结构变化和质量传输的覆盖依赖性行为
3. New insights into the Belousov-Zhabotinskii reaction derived from EQCM measurements at a gold electrode [J] . Zenonas Jusys, Stanley Bruckenstein, A. Robert Hillman Physical chemistry chemical physics: PCCP . 2011,第12期

机译：从金电极上的EQCM测量得出的Belousov-Zhabotinskii反应的新见解
4. Volatile organic compounds sensor with stacked interdigitated electrodes coated with monolayer-protected gold nanoclusters [C] . Chang C.-Y., Kuo C.-Y., Huang P.-K., International Conference on Solid-State Sensors, Actuators and Microsystems . 2013

机译：挥发性有机化合物传感器，具有交错的叉指电极，并涂有单层保护的金纳米簇
5. Electrochemical quartz crystal microbalance (EQCM) studies of films: Part 1. Ion and water transfers accompanying redox switching of Prussian Blue. Part 2. Adsorption of fibrinogen on gold modified electrodes with PPY. [D] . Kim, Ketack. 2002

机译：薄膜的电化学石英晶体微天平（EQCM）研究：第1部分。伴随普鲁士蓝的氧化还原转换而发生的离子和水转移。第2部分。纤维蛋白原在PPY修饰的金修饰电极上的吸附。
6. An Electrochemical Immunosensor for Detection of Staphylococcus aureus Bacteria Based on Immobilization of Antibodies on Self-Assembled Monolayers-Functionalized Gold Electrode [O] . Mohamed Braiek, Karima Bekir Rokbani, Amani Chrouda, 2012

机译：基于抗体在自组装单层功能金电极上固定化的金黄色葡萄球菌细菌电化学免疫传感器
7. In-situ EQCM Study on Growth of Polypyrrole Films Using Gold Electrodes Modified with Self-Assembled Monolayers in an Aqueous Solution [O] . 2002

机译：使用在水溶液中用自组装单层改性的金电极进行多吡咯膜生长的原位EQCM研究

EQCM Measurements: Redox-Induced Changes in Solvent and Ion Content in AnchoredRedox Monolayers of Organosulfur Compounds and Their Electrocatalysis on Gold Electrodes

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