首页> 美国政府科技报告 >Indium(III) Compounds Containing the Neopentyl Substituent, In(CH2CMe3)3, In(CH2CMe3)2Cl, In(CH2CMe3)Cl2 and In(CH2CMe3)2CH3. The Crystal and Molecular Structure of Dichloroneopentylindium(III), an Inorganic Polymer

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Indium(III) Compounds Containing the Neopentyl Substituent, In(CH2CMe3)3, In(CH2CMe3)2Cl, In(CH2CMe3)Cl2 and In(CH2CMe3)2CH3. The Crystal and Molecular Structure of Dichloroneopentylindium(III), an Inorganic Polymer

机译：含有新戊基取代基的铟（III）化合物，In（CH2Cme3）3，In（CH2Cme3）2Cl，In（CH2Cme3）Cl2和In（CH2Cme3）2CH3。无机聚合物二氯新戊基铟（III）的晶体和分子结构

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Organometallic chemical vapor deposition (OMCVD) is one of the most useful techniques for making compound semiconductors such as InP. The most desireable organometallic sources for OMCVD should be easily prepared,readily purified volatile liquids with excellent stability at room temperature. A number of homoleptic organoindium (III) compounds (InR3 R=Me, 3 Et, 4,5 n-Pr, 5 i-Pr, 5 n-Bu, 5 i-Bu, 5 s-Bu, 5 t-Bu 6 and Ch2SiMe3 7) are known but only InMe3 and InEt3 are readily available for use in electronic applications. However, neither InMe3 nor InEt3 has all of the desireable physical properties. Trimethylindium has the disadvantage of being a solid with a relatively high melting point of 89.5 C. In contrast, triethylindium is a liquid at room temperature (mp -32 C) but the presence of beta-hydrogen atoms on the ligands reduces its thermal stability. Both compounds have the disadvantage of being prepared by relatively involved time-consuming procedures. In an attempt to provide alternative indium sources which can be prepared and purified easily, the chemistry of indium compounds with neopentyl ligands was investigated. (mjm)

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Beachley, O. T.; Spiegel, E. F.; Kopasz, J. P.; Rogers, R. D.;
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年度 1989
页码 p.1-35
总页数 35
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Indium compounds; Inorganic polymers; Ligands; Organometallic compounds; Vapor deposition; Atoms; Chemical reactions; Chemistry; Consumption; Electronics; High temperature; Hydrogen; Indium; Liquids; Melting point; Physical properties; Room temperature; Semiconducto;

机译：铟化合物;无机聚合物;配体;有机金属化合物;气相沉积;原子;化学反应;化学;消耗;电子学;高温;氢;铟;液体;熔点;物理性质;室温;半导体;

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Indium(III) Compounds Containing the Neopentyl Substituent, In(CH2CMe3)3, In(CH2CMe3)2Cl, In(CH2CMe3)Cl2 and In(CH2CMe3)2CH3. The Crystal and Molecular Structure of Dichloroneopentylindium(III), an Inorganic Polymer

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