首页> 美国政府科技报告 >Further Developments of the Metal Vapor/Alkyl Radical Reaction. Synthesis of Tris(Trifluoromethyl)Indium and Bis(Trifluorosilyl)Cobalt and Their Base Adducts

【24h】

Further Developments of the Metal Vapor/Alkyl Radical Reaction. Synthesis of Tris(Trifluoromethyl)Indium and Bis(Trifluorosilyl)Cobalt and Their Base Adducts

机译：金属蒸气/烷基自由基反应的进一步发展。三（三氟甲基）铟和双（三氟甲硅烷基）钴及其碱加合物的合成

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

A general synthesis has been established for the preparation of bonded perfluorinated metal alkyls. Cocondensation reaction of indium vapors with carbon trifluoride radicals and cobalt vapors with SiF radicals at -196 deg. C have generated the new compounds in (CF) and Co(SiF) respectively. Addition of PMe3 to these compounds resulted in the formation of the base stabilized complexes. The synthesis and physical properties of the compounds are reported. Keywords: Metal; Alkyl; Cocondensation; Reactions; Indium; Vapors.

著录项

作者
Guerra, M. A.; Bierschenk, T. R.; Lagow, R. J.;
展开▼
作者单位

展开▼
年度 1986
页码 p.1-8
总页数 8
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Cobalt; Indium; Metal vapors; Fluorinated hydrocarbons; Synthesis(Chemistry); Stabilization; Vapors; Physical properties; Synthesis; Carbon; Chemical radicals; Response; Organometallic compounds; Reprints; Free radicals; Phosphine; Condensation reactions; Methyl rad;

机译：钴;铟;金属蒸气;氟化烃;合成（化学）;稳定化;蒸气;物理性质;合成;碳;化学基团;响应;有机金属化合物;重印;自由基;膦;缩合反应;甲基;

相似文献

外文文献
中文文献
专利

1. THE FIRST TRIFLUOROSILYL HYDRIDO TRANSITION-METAL COMPOUND - METAL ATOM SYNTHESIS AND STRUCTURE OF (ETA(6)-TOLUENE)BIS(TRIFLUOROSILYL)IRON DIHYDRIDE [J] . Yao ZG., Klabunde KJ. Organometallics . 1995,第11期

机译：（ETA（6）-甲苯）双（三氟甲硅烷基）铁二氟的首氟烷基水合过渡金属-金属原子的合成与结构
2. Coordination geometries of bis(4-amino-3-alkyl-1,2,4-triazole-5-thione) complexes of first row transition metals: crystal structures of the cobalt and nickel complexes of 4-amino-3-trifluoromethyl-1,2,4-triazole-5-thione [J] . Menzies CM., Squattrito PJ. Inorganica Chimica Acta . 2001,第1a2期

机译：第一排过渡金属的双（4-氨基-3-烷基-1,2,4-三唑-5-硫酮）配合物的配位几何：4-氨基-3-三氟甲基-1的钴和镍配合物的晶体结构，2,4-三唑-5-硫酮
3. The first alkyl bismuthates: tris(trifluoromethyl) fluoro- and tetrakis (trifluoromethyl)-bismuthate [J] . Wieland Tyrra, Dieter Naumann, Natalya V. Kirij, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第5期

机译：第一烷基铋酸盐：三（三氟甲基）氟-和四（三氟甲基）-铋
4. Chemoselective Synthesis of Novel Macrocyclic Polyether 60 Fullerene bis- and tris-Adducts by Tether-Directed Chemistry and Study of their Complexation Behavior with Alkali Metal Cations [C] . Zhiguo Zhou, David I. Schuster, Stephen R. Wilson International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters, May 12-17, 2002, Philadelphia . 2002

机译：系链导向化学化学选择性合成新型大环聚醚60富勒烯双-和三-加合物及其与碱金属阳离子的络合行为研究
5. The chemistry of alkyne adduct complexes of the cyclopentadienyl-based cobalt cluster dicobalt tris(cyclopentadienyl cobalt) [D] . King, William David 1996

机译：环戊二烯基钴簇二钴三（环戊二烯基钴）的炔烃加合物的化学性质
6. Synthesis of 510-bis(Trifluoromethyl) Substituted β-Octamethylporphyrins and Central-Metal-Dependent Solvolysis of Their meso-Trifluoromethyl Groups [O] . Masaaki Suzuki, Saburo Neya, Yutaka Nishigaichi 2016

机译：510-双（三氟甲基）取代的β-八甲基卟啉的合成及其中三氟甲基的中心金属依赖性溶剂解
7. Lewis base adducts of Group 11 metal(I) complexes. Part 48. Heterobimetallic tris(dithiocarbamato)cobalt(III)–copper(I) halide adducts as a vehicle for novel copper(I) halide clusters (structurally characterized) [O] . Healy Peter, W. Skelton Brian, H. White Allan 1989

机译：11族金属（I）配合物的路易斯碱加合物。第48部分。异双金属三（二硫代氨基甲酸酯）钴（III）-铜（I）卤化物加合物，作为新型卤化铜（I）簇的媒介物（结构表征）
8. Group IIB (12) Metal Alkyls: The Synthesis of Trifluorosilyl and Trifluoromethyl Alkyls of Cadmium and Zinc [R] . Guerra, M. A., Bierschenk, T. R., Lagow, R. J. 1986

机译：IIB组（12）金属烷基：镉和锌的三氟甲硅烷基和三氟甲基烷基的合成

Further Developments of the Metal Vapor/Alkyl Radical Reaction. Synthesis of Tris(Trifluoromethyl)Indium and Bis(Trifluorosilyl)Cobalt and Their Base Adducts

摘要

著录项

相似文献

相关主题

期刊订阅