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The Synthesis and Reactions of 2,4-Ditertiarybutyl-3-Chloro-1-Lambda(6)-Thia-2,4-Diaza-3-Phosphetidine- 1,1-Dioxide, A Heterocycle Containing Nitrogen, Sulfur, and Tricoordinate Phosphorus

机译：2,4-二叔丁基-3-氯-1-基（6） - 噻-2,4-二氮杂-3-磷杂环丁烷-1,1-二氧化物的合成及反应，含有氮，硫和三配位磷的杂环

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A new four-membered nitrogen-sulfur-phosphorus ring of composition O2S(t-BuN)2PCl has been prepared by the action of PCl3 on the sulfamide, (t-BuNH)2 SO2 in the presence of Et3N and characterized by elemental analysis, and NMR, IR, and mass spectroscopy. Reaction of the title compound with SbF3 and Me3SiNMe2 afforded the 3-fluoro and 3-dimethylamino derivatives, O2S(t-BuN)2PF and O2S(t-BuN)2PNMe, respectively, and treatment with sodium in n-octane produced the diphosphine, (O2S(t-BuN)2P)2. Treatment of the thiadiazaphosphetidine ring with Fe2(CO)9 afforded the phosphorus-iron bonded complex O2S(t-BuN)2P(Cl)Fe(CO)4. (Author)

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Cowley, A. H.; Mehrotra, S. K.; Roesky, H. W.;
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年度 1980
页码 p.1-27
总页数 27
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Synthesis(Chemistry); Reaction kinetics; Heterocyclic compounds; Nitrogen; Sulfadiazine; Butyl radicals; Phosphorus; Chlorine; Nuclear magnetic resonance; Mass spectroscopy; Metal complexes; Iron compounds; Carbonyl compounds; Amines; Phosphine; Sodium compounds;

机译：合成（化学）;反应动力学;杂环化合物;氮;磺胺嘧啶;丁基;磷;氯;核磁共振;质谱;金属配合物;铁化合物;羰基化合物;胺;膦;钠化合物;

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机译：氮杂杂环稠合的1,2,4-苯并噻二嗪-1,1-二氧化物，喹唑啉酮和吡咯烷酮衍生物与胍的连接通过顺序氮杂-Wittig反应/分子内NH加成环化/亲核取代闭环方法，使用功能化碳二亚胺作为关键中间体
2. PROPERTIES AND REACTIONS OF SUBSTITUTED 1,2-THIAZETIDINE 1,1-DIOXIDES - SYNTHESIS OF N-SUBSTITUTED 4,4-DIMETHYL-1,2-THIAZETIDIN-3-ONE 1,1-DIOXIDES, AND A NEW BASE-CATALYZED REARRANGEMENT TO THIAZOLIDIN-4-ONE 1,1-DIOXIDES [J] . Glasl D., Otto HH., Rihs G. Helvetica chimica acta . 1997,第3期

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3. Copper-Catalyzed Domino Synthesis of Nitrogen Heterocycle-Fused Benzoimidazole and 1,2,4-Benzothiadiazine 1,1-Dioxide Derivatives [J] . Yang Daoshan, An Baojuan, Wei Wei, ACS combinatorial science . 2015,第2期

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4. Synthesis of Nitrogen Heterocycles by Hetero Diels-Alder Reactions [C] . Rodolfo Nesi, Donatella Giomi, Stefania Turchi Edition of the A. Corbella" summer school on organic synthesis" . 1999

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5. Michael-terminated tandem reactions for the synthesis of nitrogen and sulfur heterocycles and substituted spiranes. [D] . Peeples, Christopher Joseph. 1991

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6. Phosphorus-Sulfur Heterocycles Incorporating an O-P(S)-O or O-P(S)-S-S-P(S)-O Scaffold: One-Pot Synthesis and Crystal Structure Study [O] . Guoxiong Hua, Kate Davidson, David B. Cordes, 2017

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7. Recent Advances in the Synthesis of Heterocycles via Reactions Involving Elemental Sulfur [O] . Thanh Binh Nguyen 2020

机译：通过涉及元素硫的反应合成杂环的最新进展

The Synthesis and Reactions of 2,4-Ditertiarybutyl-3-Chloro-1-Lambda(6)-Thia-2,4-Diaza-3-Phosphetidine- 1,1-Dioxide, A Heterocycle Containing Nitrogen, Sulfur, and Tricoordinate Phosphorus

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