首页> 美国政府科技报告 >Assessing the Salting-Out Behavior of 2,4-Dinitrobenzaldehyde and 2,6- Dinitrobenzaldehyde from Solubility Values in Pure Water and Seawater at Temperatures between (280 and 313) K
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Assessing the Salting-Out Behavior of 2,4-Dinitrobenzaldehyde and 2,6- Dinitrobenzaldehyde from Solubility Values in Pure Water and Seawater at Temperatures between (280 and 313) K

机译:在(280和313)K之间的温度下评估纯水和海水中溶解度值下2,4-二硝基苯甲醛和2,6-二硝基苯甲醛的盐析行为

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The salting-out behavior of 2,4-dinitrobenzaldehyde (2,4-DNBA) and 2, 6-dinitrobenzaldehyde (2,6-DNBA) was determined from solubility measurements in pure water and seawater with ionic strengths of (0.1662, 0.3352, 0.5071, and 0.6820) (mol middle dot)kg(- 1) at temperatures between (280 and 314) K. For both compounds tested, the solubility increased with increasing temperature. As the ionic strength of the solution increased, the solubility of the organic compounds decreased. The average salting-out coefficients for 2,4-DNBA and 2,6- DNBA were (0.12 and 0.10) kg (middle dot)mol 1, respectively, which are consistent with measurements for other nitroaromatic compounds. Over the temperature range examined, the salting-out coefficients did not vary significantly.

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