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Synthesis of Large-Pore Stabilized MIL-53(Al) Compounds with Increased CO2 Adsorption and Decreased Water Adsorption.

机译：大孔稳定mIL-53（al）化合物的合成，具有增加的CO2吸附和降低水吸附。

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This work reports two large-pore stabilized MIL-53(Al) metal-organic frameworks prepared via solvothermal synthesis strategies that possess no or only slight breathing behaviour. Powder X-ray diffraction confirmed one material remains in the large-pore form under all conditions, while the other material undergoes a more gradual breathing transition than is observed for MIL-53(Al) prepared by traditional methods. Solid-state NMR was employed to elucidate additional structural information and gain insight into the role synthesis solvent plays on breathing behaviour. The CO2 and water adsorption of these large-pore stabilized materials were studied, and the improvement in CO2 loadings over MIL-53(Al) prepared by traditional methods was discussed.

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作者
Mounfield, I.; Walton, K. S.;
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年度 2014
页码 1-11
总页数 11
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Adsorption; Aluminum compounds; Carbon dioxide; Synthesis(chemistry); Fourier transformation; Infrared radiation; Nitrogen; Nuclear magnetic resonance; Solvents; Spectroscopy; Water; X ray diffraction; Breathing mof; Solvent effects; Decreased water adsorption; Increased co2 adsorption; Co2(carbon dioxide); Large-pore stabilized mil-53 mof; Mof(metal organic frameworks); Powder xrd; Xrd(x-ray diffraction); Physisorption; Nmr(nuclear magnetic resonance); Nmr spectroscopy; Ftir spectroscopy; Ftir(fourier transformation infrared radiation); Pe622622;

机译：吸附;铝化合物;二氧化碳;合成（化学）;傅里叶变换;红外辐射;氮;核磁共振;溶剂;光谱学;水; X射线衍射;呼吸自由度;溶剂效应;降低水吸附;增加二氧化碳吸附;二氧化碳（二氧化碳）;大孔稳定的mil-53 mof; mof（金属有机骨架）;粉末xrd; Xrd（x射线衍射）;物理吸附; Nmr（核磁共振）; Nmr光谱; Ftir光谱; Ftir（傅立叶）转换红外辐射）; pe622622;

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专利

1. Adsorption Forms of CO2 on MIL-53(Al) and MIL-53(Al) OHx As Revealed by FTIR Spectroscopy [J] . Andonova Stanislava, Ivanova Elena, Yang Jie, The journal of physical chemistry, C. Nanomaterials and interfaces . 2017,第34期

机译：FTIR光谱透露的MIL-53（Al）和MIL-53（Al）OHX上的CO2的吸附形式
2. Synthesis, characterization, and CO2 adsorption of three metal-organic frameworks (MOFs): MIL-53, MIL-96, and amino-MIL-53 [J] . Abid Hussein Rasool, Rada Zana Hassan, Shang Jin, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2016,第Null期

机译：三种金属有机骨架（MOF）的合成，表征和CO2吸附：MIL-53，MIL-96和氨基-MIL-53
3. CO2 - Reinforced nanoporous carbon potential energy field during CO2/CH4 mixture adsorption. A comprehensive volumetric, in-situ IR, and thermodynamic insight [J] . Wisniewski Marek, Koter Stanislaw, Terzyk Artur P., Carbon: An International Journal Sponsored by the American Carbon Society . 2017,第期

机译：CO2 - 增强纳米多孔碳势能在CO2 / CH4混合物吸附过程中。全面的体积，原位IR和热力学洞察力
4. Investigation of Synthesis Solvent for Large-Pore Stabilized MIL-53 Compounds with Increased CO2 Adsorption and Decreased Water Adsorption [C] . William P. Mounfield III, Krista S. Walton AIChE Annual Meeting . 2014

机译：用于大孔稳定的MIL-53化合物的合成溶剂的研究随着CO 2吸附和降低水吸附而降低
5. Removal of recalcitrant contaminants from stabilized landfill leachate by a combination of advanced oxidation process (AOP) and granular activated carbon (GAC) adsorption. [D] . Kurniawan, Tonni Agustiono. 2008

机译：通过先进的氧化工艺（AOP）和颗粒活性炭（GAC）吸附相结合，从稳定的垃圾填埋场渗滤液中去除顽固性污染物。
6. Overcoming double-step CO2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg2(dobpdc) [O] . Phillip J. Milner, Jeffrey D. Martell, Rebecca L. Siegelman, 2018

机译：Mg2（dobpdc）的笨重的二胺添加变体中克服了CO2的两步吸附并最小化了水的共吸附
7. CO2 - Reinforced nanoporous carbon potential energy field during CO2/CH4 mixture adsorption. A comprehensive volumetric, in-situ IR, and thermodynamic insight [O] . Marek Wiśniewski, Stanisław Koter, Artur P. Terzyk, 2017

机译：CO2 - 增强纳米多孔碳电位能场在CO2 / CH4混合物吸附过程中。全面的体积，原位IR和热力学洞察力

Synthesis of Large-Pore Stabilized MIL-53(Al) Compounds with Increased CO2 Adsorption and Decreased Water Adsorption.

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