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Chemical reactivity of potential ferrocyanide precipitates in Hanford tanks with nitrates and nitrites

机译：潜在亚铁氰化物的化学反应性在Hanford罐中与硝酸盐和亚硝酸盐一起沉淀

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Ferrocyanide-bearing wastes were produced at the Hanford Site during the 1950s. Safe storage of these wastes has recently drawn increased attention. As a result of these concerns, the Pacific Northwest Laboratory was chartered to investigate the chemical reactivity and explosivity of the ferrocyanide bearing wastes. We have investigated the thermal sensitivity of synthetic wastes and ferrocyanides and observed oxidation at 130(degrees)C and explosions down to 295(degrees)C. Coupled with thermodynamic calculations, these thermal studies have also shown a dependence of the reactivity on the synthetic waste composition, which is dependent on the solids settling behavior.

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Scheele, R. D.; Tingey, J. M.; Lilga, M. A.; Burger, L. L.; Hallen, R. T.;
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年度 1992
页码 1-16
总页数 16
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Ferrocyanides ; Hanford Reservation ; Waste Storage ; Chemical Reactions ; Chemical Wastes ; Explosions ; Nitrates ; Nitrites ; Oxidation ; Precipitation ; Tanks ; Thermodynamics ; Meetings;

机译：亚铁氰化物;汉福德保留;废物贮存;化学反应;化学废物;爆炸;硝酸盐;亚硝酸盐;氧化;沉淀;储罐;热力学;会议;

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2. Heterologous expression and biochemical characterization of assimilatory nitrate and nitrite reductase reveals adaption and potential of Bacillus megaterium NCT-2 in secondary salinization soil [J] . Chu Shaohua, Zhang Dan, Wang Daxin, International Journal of Biological Macromolecules: Structure, Function and Interactions . 2017,第期

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4. ROBUST CHEMICAL REACTIVITY PROGRAM PREVENTS POTENTIAL TANK EXPLOSION [C] . John C. Wincek Institution of Chemical Engineers symposium on hazards . 2011

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7. DOE FG02-03ER63557: Final Technical Report: Reactivity of Primary Soil Minerals and Secondary Precipitates Beneath Leaking Hanford Waste Tanks [O] . Nagy, Kathryn L. 2009

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8. Chemical reactivity of potential ferrocyanide precipitates in Hanford tanks with nitrates and nitrites [R] . Scheele, R D, Tingey, J M, Lilga, MA, 1992

机译：潜在亚铁氰化物的化学反应性在Hanford罐中与硝酸盐和亚硝酸盐一起沉淀

Chemical reactivity of potential ferrocyanide precipitates in Hanford tanks with nitrates and nitrites

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