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Biomimetic Catalysis: Hydroxylation of C2 , C3 , and CycloC6 Hydrocarbons by Managanese Porphyrin and Non-Porphyrin Catalysts in the Presence of Monooxygen Transfer Reagents.

机译：仿生催化：在单氧转移试剂存在下，锰卟啉和非卟啉催化剂对C2，C3和CycloC6碳氢化合物进行羟基化反应。

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Metal complexes that mimic the active site of monooxygenase enzymes and convert carbon-hydrogen bonds to carbon-hydroxyl in the presence of a monooxygen transfer reagent are called biomimetic catalysts. Studies concerning the activation of methane, ethane, propane, and cyclohexane to their respective alcohols with biomimetic catalysts that encompass manganese supramolecule porphyrins and open-faced porphyrins, manganese non-porphyrin tri and tetranuclear clusters and a mononuclear manganese-substituted Keggin ion in the presence of monooxygen transfer reagents such as iodosylbenzene and t-butyl hydroperoxide will be discussed. 6 refs., 1 fig., 3 tabs.

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Fish, R. H.; Fong, R. H.; Price, R. T.; Vincent, J. B.; Christou, G.;
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年度 1988
页码 1-13
总页数 13
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Catalysts; Cyclohexane; Ethane; Methane; Propane; Alcohols; Biomimetic Processes; Chemical Reactions; Hydroxylation; Manganese Complexes; Porphyrins; ERDA/140505;

机译：催化剂;环己烷;乙烷;甲烷;丙烷;醇类;仿生过程;化学反应;羟基化;锰配合物;卟啉; ERDa / 140505;

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专利

1. Chemoselective and biomimetic hydroxylation of hydrocarbons by non-heme μ-oxo-bridged diiron(III) catalysts using m-CPBA as oxidant [J] . Ramasamy Mayilmurugan, Helen Stoeckli-Evans, Eringathodi Suresh, Dalton transactions: An international journal of inorganic chemistry . 2009,第26期

机译：以m-CPBA为氧化剂的非血红素μ-氧代桥联二铁（III）催化剂对烃类的化学选择性和仿生羟基化
2. Asymmetric Catalysis by a Chiral Ruthenium Porphyrin: Epoxidation, Hydroxylation, and Partial Kinetic Resolution of Hydrocarbons [J] . Zeev Gross, Santiago Ini Organic letters . 1999,第13期

机译：手性钌卟啉的不对称催化：烃的环氧化，羟基化和部分动力学拆分。
3. Au/MCr2O4 (M = Co, Mn, Fe) catalysts in the oxidations of CO, C2, and C3 hydrocarbons [J] . B. Grzybowska-Swierkosz, M. Ruszel, R. Grabowski Reaction kinetics,mechanisms and catalysis . 2012,第1期

机译：Au / MCr2O4（M = Co，Mn，Fe）催化剂可氧化CO，C2和C3碳氢化合物
4. Development of surface reaction mechanism of exhaust hydrocarbon species based on surface and gaseous species analysis: Reactions of C2 and C3 hydrocarbon species on Pt/Al2O3 catalyst [C] . KRISTYAWAN I Putu Angga, NAING Set 燃焼シンポジウム . 2018

机译：基于表面和气态物质的排气烃物质表面反应机理的发展：C2和C3烃物种对Pt / Al2O3催化剂的反应
5. FREE RADICAL CHLORINATION AND EPOXIDATION OF HYDROCARBONS BY INORGANIC HYPOCHLORITE IN THE PRESENCE OF A PHASE TRANSFER CATALYST. [D] . FONOUNI, HOSSEIN E. 1983

机译：存在相转移催化剂时，无机亚氯酸盐对烃的自由基氯化和环氧化反应。

Biomimetic Catalysis: Hydroxylation of C2 , C3 , and CycloC6 Hydrocarbons by Managanese Porphyrin and Non-Porphyrin Catalysts in the Presence of Monooxygen Transfer Reagents.

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